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Merck
모든 사진(2)

문서

466867

Sigma-Aldrich

Polybutadiene, predominantly 1,2-addition

approx. 90% 1,2-vinyl

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About This Item

Linear Formula:
[CH2CH(CH=CH2)]n
CAS Number:
MDL number:
UNSPSC 코드:
12162002
PubChem Substance ID:
NACRES:
NA.23

Quality Level

refractive index

n20/D 1.5002 (lit.)

점도

30-100 poise(45 °C)(lit.)

전이 온도

Tg −30 °C

density

0.86 g/mL at 25 °C (lit.)

SMILES string

C=CC=C

InChI

1S/C4H8/c1-3-4-2/h3-4H,1-2H3/b4-3+

InChI key

IAQRGUVFOMOMEM-ONEGZZNKSA-N

애플리케이션

  • Transforming Polybutadiene with Tetrazine Click Chemistry into Antioxidant Foams That Fluoresce with Oxidation: This research uses tetrazine click chemistry to modify polybutadiene, enhancing its properties to create antioxidant foams that respond to oxidation with fluorescence, demonstrating innovative ways to utilize 1,2-addition polybutadiene (RE Bagge et al., 2017).
  • Isoxazoline-based porous polymer for the highly effective adsorption of 2,4,6-trinitrotoluene (TNT): Catalyst-free click polymerization between an in situ generated nitrile oxide with polybutadiene. This article explores the enhancement of polybutadiene′s adsorptive properties for environmental cleanup applications, emphasizing how its structural characteristics affect performance (H Deng et al., 2020).
  • Modification of polybutadiene with trifluoromethyl and clickable azide groups in one shot: This paper describes the simultaneous introduction of trifluoromethyl and azide functional groups into polybutadiene, showcasing the versatility of 1,2-addition polybutadiene in chemical modifications (S Wang et al., 2021).

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Gloves, type N95 (US)


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문서 라이브러리 방문

Zhi-ping Huang et al.
Journal of hazardous materials, 229-230, 251-257 (2012-06-26)
Migration appeared in the interfaces of nitrate ester plasticized polyether (NEPE) based propellant/hydroxyl-terminated polybutadiene (HTPB) based liner/ethylene propylene terpolymer (EPDM) based insulation was studied by aging at different temperatures. The migration components were extracted with solvent and determined by high
Li Li et al.
ACS nano, 5(10), 7754-7766 (2011-08-27)
Understanding the relevant permeability properties of ultrafiltration membranes is facilitated by using materials and procedures that allow a high degree of control on morphology and chemical composition. Here we present the first study on diffusion permeability through gyroid nanoporous cross-linked
Rachel Calvet et al.
Journal of chromatography. A, 1253, 164-170 (2012-07-24)
In this study, the coupling of IGC-ID analysis and carbon blacks impregnation with increasing ratios of polymer allow us to highlight the affinity of the polymer to the solid surface. The variations of the dispersive component of the surface energy
Gregory P Robbins et al.
Langmuir : the ACS journal of surfaces and colloids, 26(17), 14089-14096 (2010-08-14)
The polymersome, a fully synthetic cell mimetic, is a tunable platform for drug delivery vehicles to detect and treat disease (theranostics). Here, we design a leuko-polymersome, a polymersome with the adhesive properties of leukocytes, which can effectively bind to inflammatory
Joan M Widin et al.
Journal of the American Chemical Society, 134(8), 3834-3844 (2012-01-28)
Controlled/"living" polymerizations and tandem polymerization methodologies offer enticing opportunities to enchain a wide variety of monomers into new, functional block copolymer materials with unusual physical properties. However, the use of these synthetic methods often introduces nontrivial molecular weight polydispersities, a

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