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Merck
모든 사진(2)

주요 문서

520853

Sigma-Aldrich

Potassium tetrachloroplatinate(II)

≥99.9% trace metals basis

동의어(들):

Potassium platinum(II) chloride

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About This Item

Linear Formula:
K2PtCl4
CAS Number:
Molecular Weight:
415.09
EC Number:
MDL number:
UNSPSC 코드:
12352302
PubChem Substance ID:
NACRES:
NA.23
분석:
≥99.9% trace metals basis
양식:
powder or crystals

Quality Level

분석

≥99.9% trace metals basis

양식

powder or crystals

구성

Pt, ≥46.2%

불순물

≤1000.0 ppm Trace Metal Analysis

density

3.38 g/mL at 25 °C (lit.)

SMILES string

[K+].[K+].Cl[Pt--](Cl)(Cl)Cl

InChI

1S/4ClH.2K.Pt/h4*1H;;;/q;;;;2*+1;+2/p-4

InChI key

RVRDLMCWUILSAH-UHFFFAOYSA-J

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일반 설명

Potassium tetrachloroplatinate(II) is a crystalline solid that is insoluble in water and soluble in organic solvents. It is widely used in the field of nanomaterial synthesis, catalysis, and energy storage.

애플리케이션

Potassium tetrachloroplatinate(II) can be used:
  • As a precursor to prepare platinum nanoparticles and mesoporous platinum nanospheres with tunable pore sizes.
  • As a catalyst for selective methane oxidation through C-H activation. In addition, to synthesize octahedral [email protected] nanocrystals with an ultrathin PtNi alloy shell. The nanocrystals exhibited better ORR activity and durability than the commercial Pt/C for fuel cells.
  • To prepare Pt atomic clusters were synthesized using a one-step carbon-defect-driven electroless deposition method. These catalysts demonstrated low overpotential, high activity for the hydrogen evolution reaction, exceptional stability, and improved utilization efficiency of Pt. The Pt-AC/DG (Atomic Clusters/Defective Graphene) cathode showed excellent hydrogen production activity, remarkable stability, and significantly reduced Pt usage compared to the Pt/C catalyst.
  • As a starting material to synthesize cyclometalated platinum(II) complexes with long-lived luminescence in solution.

특징 및 장점

Reacts with bis(dithiolates) to form metal-bis(dithiolates) with applications in laser Q-switch materials, liquid crystals, optical CD recording media, bar code materials and superconductivity. Reacts with capping polymers to form shape-control colloidal platinum nanoparticles for catalysis and photocatalysts.

픽토그램

Skull and crossbonesHealth hazardCorrosion

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 1

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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시험 성적서(COA)

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문서 라이브러리 방문

Alkyl chain functionalised, cyclometalated platinum(II) complexes: Syntheses, luminescence properties and X-ray crystal structure
Juliette A. Lowe, et al.
Journal of Organometallic Chemistry, 805, 87-93 (2016)
Carbon-Defect-Driven Electroless Deposition of Pt Atomic Clusters for Highly Efficient Hydrogen Evolution
Qingqing Cheng, et al.
Journal of the American Chemical Society, 142, 5594-5601 (2020)
Selective Methane Oxidation Catalyzed by Platinum Salts in Oleum at Turnover Frequencies of Large-Scale Industrial Processes
Tobias Zimmermann, et al.
Journal of the American Chemical Society, 138, 12395-12400 (2016)
Polymeric micelle assembly for the smart synthesis of mesoporous platinum nanospheres with tunable pore sizes
Yunqi Li, et al.
Angewandte Chemie (International Edition in English), 54, 11073-11077 (2015)
H C Schuppe et al.
International archives of allergy and immunology, 112(2), 125-132 (1997-02-01)
The sensitizing properties of different complex salts of platinum were defined in vivo by means of the popliteal lymph node (PLN) assay in mice. Hexa- and tetrachloroplatinates were confirmed to be highly immunogenic, inducing vigorous primary immune responses in the

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