590231

Di(acetato)dicyclohexylphenylphosphinepalladium(II), polymer-bound FibreCat^®

Pd ~5 %, extent of labeling: 0.4-0.6 mmol/g PPH₃ ligand content loading

• CAS Number: 480445-43-0
• MDL number: MFCD04118909
• UNSPSC 코드: 12352103
• NACRES: NA.22

속성

• 제품 라인: FibreCat^®
• Quality Level: 100
• 양식: solid
• 구성: Pd, ~5%
• 반응 적합성: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reaction type: solution phase peptide synthesis; reagent type: catalyst; reaction type: Coupling Reactions
• 라벨링 범위: 0.4-0.6 mmol/g PPH₃ ligand content loading
• SMILES string: [Pd+2].P(C3CCCCC3)(C2CCCCC2)c1ccccc1.[O-]C(=O)C.[O-]C(=O)C
• InChI key: ZMMYBYFXUHUTSH-UHFFFAOYSA-L

설명

애플리케이션

Supported catalyst used in Suzuki coupling of less reactive aryl chloride with boronic acids. This supported catalyst is generally more selective than the free homogeneous catalyst, and palladium leaching is very low (<2 ppm).

The resin can also be recycled.

법적 정보

FibreCat is a registered trademark of Johnson Matthey PLC

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Gloves, type N95 (US)