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Merck
모든 사진(1)

주요 문서

609374

Sigma-Aldrich

Sodium azide-1-15N

(terminal N), 98 atom % 15N

동의어(들):

Sodium azide-15N1 (terminal N)

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About This Item

Linear Formula:
(Na+)(15N≡NN-)
Molecular Weight:
66.00
EC Number:
UNSPSC 코드:
12352125
PubChem Substance ID:
NACRES:
NA.12

Quality Level

동위원소 순도

98 atom % 15N

분석

95% (CP)

bp

300 °C

mp

275 °C

density

1.87 g/mL at 25 °C

질량 이동

M+2

SMILES string

[Na]N=[N+]=[15N-].[Na][15N]=[N+]=[N-]

InChI

1S/2N3.2Na/c2*1-3-2;;/q2*-1;2*+1/i2*1+1;;

InChI key

CHVYWISGAZDJOG-ZIVIQNEDSA-N

일반 설명

Sodium azide-1-15N is isotopically labeled analogue of sodium azide.

포장

This product may be available from bulk stock and can be packaged on demand. For information on pricing, availability and packaging, please contact Stable Isotopes Customer Service.

픽토그램

Skull and crossbonesHealth hazardEnvironment

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2 Oral

표적 기관

Brain

보충제 위험성

Storage Class Code

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 2

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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문서 라이브러리 방문

Klaus Banert et al.
Angewandte Chemie (International ed. in English), 59(30), 12315-12320 (2020-03-27)
With the help of selective 15 N labeling experiments, it has been confirmed that nucleophilic attack of azide at iminium-activated organic azides leads to short-lived hexazene intermediates. Such species do not only tend to a cleavage reaction with formation of
Jingzhen Du et al.
Nature communications, 12(1), 5649-5649 (2021-09-26)
Determining the nature and extent of covalency of early actinide chemical bonding is a fundamentally important challenge. Recently, X-ray absorption, electron paramagnetic, and nuclear magnetic resonance spectroscopic studies have probed actinide-ligand covalency, largely confirming the paradigm of early actinide bonding
Christian E Halbig et al.
Molecules (Basel, Switzerland), 20(12), 21050-21057 (2015-12-26)
In the last decades, organic azides haven proven to be very useful precursors in organic chemistry, for example in 1,3-dipolar cycloaddition reactions (click-chemistry). Likewise, azides can be introduced into graphene oxide with an almost intact carbon framework, namely oxo-functionalized graphene
Siegfried Eigler et al.
Nanoscale, 5(24), 12136-12139 (2013-10-29)
We present the first example of azide functionalization on the surface of graphene oxide (GO), which preserves thermally unstable groups in GO through the mild reaction with sodium azide in solids. Experimental evidence, by (15)N solid-state NMR and other spectroscopic

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