662623

Bis[rhodium(α,α,α′,α′-tetramethyl-1,3-benzenedipropionic acid)]

95%

• 동의어(들): Rh₂(esp)₂
• 실험식(Hill 표기법): C₃₂H₄₀O₈Rh₂
• CAS Number: 819050-89-0
• Molecular Weight: 758.47
• MDL number: MFCD08457636
• UNSPSC 코드: 12161600
• PubChem Substance ID: 24884595
• NACRES: NA.22

속성

• 분석: 95%
• 형태: solid
• 반응 적합성: core: rhodium; reagent type: catalyst; reaction type: C-H Activation
• mp: >300 °C
• SMILES string: [Rh][Rh].CC(C)(Cc1cccc(CC(C)(C)C(O)=O)c1)C(O)=O.CC(C)(Cc2cccc(CC(C)(C)C(O)=O)c2)C(O)=O
• InChI: 1S/2C16H22O4.2Rh/c2*1-15(2,13(17)18)9-11-6-5-7-12(8-11)10-16(3,4)14(19)20;;/h2*5-8H,9-10H2,1-4H3,(H,17,18)(H,19,20);;
• InChI key: OBMUTUNJWNQIAJ-UHFFFAOYSA-N

설명

일반 설명

Bis[rhodium(α,α,α′,α′-tetramethyl-1,3-benzenedipropionicacid)] has been identified as efficient C-H activation catalyst.

애플리케이션

Rh2(esp)2: An Exceptionally Efficient and Selective Catalyst for C-H Amination

Bis[rhodium(α,α,α′,α′-tetramethyl-1,3-benzenedipropionicacid)] is used as a catalyst for oxidative C−H amination of urea and guanidinederived substrates to yield corresponding heterocyclic products.

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Gloves, type N95 (US)