추천 제품
![Bis[rhodium(α,α,α′,α′-tetramethyl-1,3-benzenedipropionic acid)] 95%](/deepweb/assets/sigmaaldrich/product/structures/102/178/d1171a49-0358-406b-8b32-04324dbf9c02/640/d1171a49-0358-406b-8b32-04324dbf9c02.png)
Quality Level
분석
99.9% trace metals basis
형태
powder
반응 적합성
reaction type: C-H Activation
reagent type: catalyst
SMILES string
CC(=O)O[Rh]OC(C)=O.CC(=O)O[Rh]OC(C)=O
InChI
1S/4C2H4O2.2Rh/c4*1-2(3)4;;/h4*1H3,(H,3,4);;/q;;;;2*+2/p-4
InChI key
SYBXSZMNKDOUCA-UHFFFAOYSA-J
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애플리케이션
Catalyst for Rh-mediated C-H activation
Effective catalyst for ylide formation.
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Gloves, type N95 (US)
시험 성적서(COA)
제품의 로트/배치 번호를 입력하여 시험 성적서(COA)을 검색하십시오. 로트 및 배치 번호는 제품 라벨에 있는 ‘로트’ 또는 ‘배치’라는 용어 뒤에서 찾을 수 있습니다.
이미 열람한 고객
Rhodium carbenoid mediated C-H activation of a tertiary methyl group: an enantiospecific approach to the angular triquinanes norsilphiperfolane and norcameroonanes
Srikrishna, A.; et al.
Synlett, 16, 2343-2346 (2011)
Jaroslav V Burda et al.
Journal of inorganic biochemistry, 102(1), 53-62 (2007-08-19)
In our study, we have determined the thermodynamic behavior for the replacement reaction of one and two acetyl-ligands from the diaqua-tetrakis(mu-acetylato)dirhodium(II,II) complex by purine DNA bases. The complexes were optimized at the density functional theory (DFT) level with the B3LYP
DNA cleavage by photogenerated Rh(2)(O(2)CCH(3))(4)(H(2)O)(2)(+).
P K Fu et al.
Inorganic chemistry, 40(11), 2476-2477 (2001-05-15)
Mijeong Kang et al.
Biochemistry, 47(8), 2265-2276 (2008-02-01)
The 2D NMR analysis in solution of the DNA duplex d(CTCTC*A*ACTTCC).d(GGAAGTTGAGAG) binding to the dirhodium unit cis-[Rh2(mu-O2CCH3)2(eta1-O2CCH3)]+ showed that an unprecedented intrastrand adduct, dsII, is formed with the dirhodium unit cross-linking in the major groove residues C5 and A6 (indicated
T Yakura
Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan, 120(12), 1309-1322 (2001-02-24)
This review summarizes novel stereoselective syntheses of 3,4-cis- and 3,4-trans-3-alkyl-4-silyloxycyclopentanones using a dirhodium(II)-catalyzed intramolecular C-H insertion reaction as a key reaction. Treatment of diazoketoesters (20a-e) with 1 mol % of dirhodium(II) tetraacetate gave 2,3-trans-3,4-cis-cyclopentanones (21a-e) as major products. The presence
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