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Merck
모든 사진(2)

주요 문서

686034

Sigma-Aldrich

Lithium aluminum hydride

greener alternative

hydrogen-storage grade

동의어(들):

LAH, Lithium alanate, Lithium tetrahydroaluminate

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About This Item

Linear Formula:
LiAlH4
CAS Number:
Molecular Weight:
37.95
EC Number:
MDL number:
UNSPSC 코드:
26111700
PubChem Substance ID:
NACRES:
NA.23

Grade

hydrogen-storage grade

Quality Level

분석

>99.95%

형태

pellets

반응 적합성

reagent type: reductant

환경친화적 대안 제품 특성

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

125 °C (dec.) (lit.)

환경친화적 대안 카테고리

SMILES string

[Li].[AlH3]

InChI

1S/Al.Li.4H/q-1;+1;;;;

InChI key

OCZDCIYGECBNKL-UHFFFAOYSA-N

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일반 설명

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

애플리케이션

Lithium aluminum hydride (LAH) is majorly used in hydrogen storage applications. Its properties include high gravimetric and volumetric hydrogen densities. It can also be used as a reducing agent in the preparation of reduced graphene oxide (rGO).

분석 메모

Hydrogen content, XRD plots and metal purity data are available upon request.

픽토그램

FlameCorrosion

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1A - Water-react 1

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 1

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable


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시험 성적서(COA)

Lot/Batch Number

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문서 라이브러리 방문

Lithium aluminum hydride as reducing agent for chemically reduced graphene oxides
Ambrosi A, et al.
Chemistry of Materials, 24(12), 2292-2298 (2012)
Reversible hydrogen storage via titanium-catalyzed LiAlH4 and Li3AlH6
Chen J, et al.
The Journal of Physical Chemistry B, 105(45), 11214-11220 (2001)
A first-principles study of the electronic structure and stability of a lithium aluminum hydride for hydrogen storage
Song Y, et al.
The Journal of Physical Chemistry B, 110(13), 6906-6910 (2006)
Regeneration of lithium aluminum hydride
Graetz J, et al.
Journal of the American Chemical Society, 130(52), 17790-17794 (2008)
Sonja Stanković et al.
Organic & biomolecular chemistry, 8(19), 4266-4273 (2010-08-05)
A new synthetic protocol for the LiAlH(4)-promoted reduction of non-activated aziridines under microwave conditions was developed. Thus, ring opening of 2-(acetoxymethyl)aziridines provided the corresponding beta-amino alcohols, which were then used as eligible substrates in the synthesis of 5-methylmorpholin-2-ones via condensation

문서

Mechanochemical Effect of Severe Plastic Deformations: Metal Alloys, Hydrides and Molecular Solids

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