추천 제품
형태
liquid
Quality Level
반응 적합성
reagent type: reductant
농도
1.0 M in THF
density
0.905 g/mL at 25 °C
저장 온도
2-30°C
SMILES string
[Li+].[AlH4-]
InChI
1S/Al.Li.4H/q-1;+1;;;;
InChI key
OCZDCIYGECBNKL-UHFFFAOYSA-N
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애플리케이션
Reactant or reagent for:
LAH is a powerful reducing agent for many different reduction reactions such as that of ketones to alcohols
- The preparation of thermoplastic polyester polyamides from oleic acid
- Lithium-polymer batteries
- Hydrodefluorination of gem-difluoromethylene derivatives
- Asymmetric aldol reactions
- Synthesis of Li-Al-N-H composites with hydrogen absorption / desorption properties
LAH is a powerful reducing agent for many different reduction reactions such as that of ketones to alcohols
포장
The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
법적 정보
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
표적 기관
Central nervous system, Respiratory system
보충제 위험성
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 1
Flash Point (°F)
1.4 °F - closed cup
Flash Point (°C)
-17 °C - closed cup
이미 열람한 고객
Hao Yao et al.
Journal of electron microscopy, 60(6), 375-378 (2011-10-05)
A plastic bag method was developed to observe air-sensitive samples on microstructure and phase distribution without exposure to air during the holder transfer process into the transmission electron microscope (TEM). As an example, a type of lithium aluminum hydride (Li(3)AlH(6))
José M Concellón et al.
The Journal of organic chemistry, 71(17), 6420-6426 (2006-08-12)
The reaction of chiral (2R,1'S)- or (2S,1'S)-2-(1-aminoalkyl)epoxides, 1 or 2 with a variety of organolithium compounds to obtain the corresponding (alphaS,betaS)- or (alphaR,betaS)- beta-amino alcohols in enantiopure form is reported. In both cases, the opening of the oxirane ring at
Haruki Sashida et al.
Chemical & pharmaceutical bulletin, 52(1), 57-62 (2004-01-08)
The reactions of the 2-benzoselenopyrylium (1A) and 2-benzotelluropyrylium cations (1B) with a variety of nucleophiles have been investigated. LiAlH(4), sodium alkoxide (NaOMe, NaOi-Pr and NaOt-Bu), diethylamine, n-butylamine and acetone reacted with 1 to give the 1H-isochromenes (2) and the corresponding
I-Chi Lee et al.
Organic & biomolecular chemistry, 9(22), 7655-7658 (2011-09-17)
Specific deuterated reference compounds were prepared to probe the stereoselectivity of the reductive ring opening of carbohydrate-based benzylidene-type acetals. AlD(3) revealed a retentive stereoselectivity probably through the rare S(N)i (internal nucleophilic substitution) mechanism. An S(N)1-like mechanism occurs in the acid-promoted
Takashi Ikegami et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 804(1), 197-201 (2004-04-20)
Bisphenol A (BPA) recognition materials were synthesized by a covalent imprinting technique using BPA-dimethacrylate or BPA-diacrylate as the template monomer. Binding sites in the polymers consisted of two hydroxyl groups that are generated by reducing the ester bonds of the
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