73022
2,6-Diisopropylphenylimido-neophylidene[(S)-(−)-BIPHEN]molybdenum(VI)
ringclosing metathesis catalyst, ≥95.0% (C)
동의어(들):
(S)-Schrock-Hoveyda Catalyst
로그인조직 및 계약 가격 보기
모든 사진(1)
About This Item
실험식(Hill 표기법):
C46H61MoNO2
CAS Number:
Molecular Weight:
755.92
MDL number:
UNSPSC 코드:
12352005
PubChem Substance ID:
NACRES:
NA.22
추천 제품
 95%](/deepweb/assets/sigmaaldrich/product/structures/151/609/eeb99dc1-9ef2-49d8-b255-6b5e2519fee1/640/eeb99dc1-9ef2-49d8-b255-6b5e2519fee1.png)
Quality Level
분석
≥95.0% (C)
양식
solid
작용기
phenyl
저장 온도
2-8°C
SMILES string
CC(C)c1cccc(C(C)C)c1N=[Mo]2(Oc3c(cc(C)c(C)c3-c4c(C)c(C)cc(c4O2)C(C)(C)C)C(C)(C)C)=CC(C)(C)c5ccccc5
InChI
1S/C24H34O2.C12H17N.C10H12.Mo/c1-13-11-17(23(5,6)7)21(25)19(15(13)3)20-16(4)14(2)12-18(22(20)26)24(8,9)10;1-8(2)10-6-5-7-11(9(3)4)12(10)13;1-10(2,3)9-7-5-4-6-8-9;/h11-12,25-26H,1-10H3;5-9H,1-4H3;1,4-8H,2-3H3;/q;;;+2/p-2
InChI key
YLWIQLXPHIAIEN-UHFFFAOYSA-L
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포장
Bottomless glass bottle. Contents are inside inserted fused cone.
기타 정보
Catalyst for the enantioselective olefin metathesis
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Gloves, type N95 (US)
이미 열람한 고객
![Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene][[5-[(dimethylamino)sulfonyl]-2-(1-methylethoxy-O)phenyl]methylene-C]ruthenium(II)](/deepweb/assets/sigmaaldrich/product/structures/179/573/f48a2a1e-cf09-4151-8b78-2bab614efd5c/640/f48a2a1e-cf09-4151-8b78-2bab614efd5c.png)
G.S. Weatherhead et al.
Tetrahedron Letters, 41, 9553-9553 (2000)
D. S. La et al.
Journal of the American Chemical Society, 120, 9720-9720 (1998)
D S La et al.
Journal of the American Chemical Society, 123(32), 7767-7778 (2001-08-09)
Studies regarding the first examples of catalytic asymmetric ring-opening metathesis (AROM) reactions are detailed. This enantioselective cleavage of norbornyl alkenes is followed by an intermolecular cross metathesis with a terminal olefin partner; judicious selection of olefin is required so that
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