762261
Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene][[5-[(dimethylamino)sulfonyl]-2-(1-methylethoxy-O)phenyl]methylene-C]ruthenium(II)
동의어(들):
Zhan Catalyst-1B
로그인조직 및 계약 가격 보기
모든 사진(4)
About This Item
실험식(Hill 표기법):
C33H43Cl2N3O3RuS
CAS Number:
Molecular Weight:
733.75
MDL number:
UNSPSC 코드:
12161600
PubChem Substance ID:
NACRES:
NA.22
추천 제품
양식
solid
Quality Level
반응 적합성
core: ruthenium
reagent type: catalyst
SMILES string
[Ru+2](=C2N(CCN2c4c(cc(cc4C)C)C)c3c(cc(cc3C)C)C)=Cc1c(ccc(c1)[S](=O)(=O)N(C)C)OC(C)C.[Cl-].[Cl-]
InChI
1S/C21H26N2.C12H17NO3S.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-9(2)16-12-7-6-11(8-10(12)3)17(14,15)13(4)5;;;/h9-12H,7-8H2,1-6H3;3,6-9H,1-2,4-5H3;2*1H;/q;;;;+2/p-2
InChI key
OXLURKCRXVAJQS-UHFFFAOYSA-L
애플리케이션
Zhan Catalyst-1B (Hoveyda-Grubbs type catalyst) can be used:
- In the preparation of hybrid olefin metathesis catalysts, with increased catalytic activity via immobilization on molecular seives. supports
- As a catalyst in the synthesis of divergent dendrimer
- In ring-closure metathesis (RCM) reaction.
Storage Class Code
13 - Non Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
이미 열람한 고객
Stereoselectivity in N-iminium ion cyclization: development of an efficient synthesis of ?-cephalotaxine
Liu H, et al.
Organic Letters, 17(18), 4444-4447 (2015)
Hoveyda-Grubbs type metathesis catalyst immobilized on mesoporous molecular sieves-The influence of pore size on the catalyst activity
Shinde T, et al.
Catalysis Today, 179(1), 123-129 (2012)
Oliver Kreye et al.
Macromolecular rapid communications, 35(3), 317-322 (2013-12-21)
The combination of the Passerini reaction and olefin cross-metathesis is shown to be a very useful approach for the divergent synthesis of dendrimers. Castor oil-derived platform chemicals, such as 10-undecenoic acid and 10-undecenal, are reacted in a Passerini reaction with
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