추천 제품
product name
D-Proline, ReagentPlus®, ≥99%
제품 라인
ReagentPlus®
분석
≥99%
형태
powder
광학 활성
[α]22/D +85.0°, c = 4 in H2O
광학 순도
ee: 98% (GLC)
반응 적합성
reaction type: solution phase peptide synthesis
mp
223 °C (dec.) (lit.)
응용 분야
peptide synthesis
SMILES string
OC(=O)[C@H]1CCCN1
InChI
1S/C5H9NO2/c7-5(8)4-2-1-3-6-4/h4,6H,1-3H2,(H,7,8)/t4-/m1/s1
InChI key
ONIBWKKTOPOVIA-SCSAIBSYSA-N
유사한 제품을 찾으십니까? 방문 제품 비교 안내
애플리케이션
D-Proline is a key starting material in the total synthesis of (−)-secu′amamine A and (R)-harmicine.
- It can be used as a ligand for the synthesis of chiral polyoxometalate (POM) clusters.
- It can also be used as a catalyst in the enantioselective α-aminoxylation of aldehydes.
법적 정보
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Gloves, type N95 (US)
시험 성적서(COA)
제품의 로트/배치 번호를 입력하여 시험 성적서(COA)을 검색하십시오. 로트 및 배치 번호는 제품 라벨에 있는 ‘로트’ 또는 ‘배치’라는 용어 뒤에서 찾을 수 있습니다.
이미 열람한 고객
Science (New York, N.Y.), 369(6504), 725-730 (2020-08-09)
Nucleoside analogs are commonly used in the treatment of cancer and viral infections. Their syntheses benefit from decades of research but are often protracted, unamenable to diversification, and reliant on a limited pool of chiral carbohydrate starting materials. We present
Synthesis of (S)?and (R)?Harmicine from Proline: An Approach Toward Tetrahydro?β?carbolines.
European Journal of Organic Chemistry, 2014(11), 2357-2364 (2014)
A Facile and Rapid Route to Highly Enantiopure 1, 2?Diols by Novel Catalytic Asymmetric α?Aminoxylation of Aldehydes.
Angewandte Chemie (International Edition in English), 115(35), 4379-4382 (2003)
Total Synthesis of the Securinega Alkaloid (−)-Secu?amamine A.
Journal of the American Chemical Society, 130(24), 7562-7563 (2008)
Chiral 3D architectures with helical channels constructed from polyoxometalate clusters and copper?amino acid complexes.
Angewandte Chemie (International Edition in English), 118(6), 918-922 (2006)
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