923524

(tBuMPhos)PdCl₂

• 동의어(들): 1-Diadamantylphosphino-1′-di-tert-butylphosphinoferrocene palladium dichloride
• 실험식(Hill 표기법): C₃₈H₅₆Cl₂FeP₂Pd
• Molecular Weight: 807.97
• UNSPSC 코드: 12352200
• NACRES: NA.21

속성

• 양식: powder
• Quality Level: 100
• 환경친화적 대안 제품 특성: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• 환경친화적 대안 카테고리: Aligned
• SMILES string: [Cl-][Pd+2]1([Cl-])[P](C(C)(C)C)(C(C)(C)C)[C-]23[CH]4=[CH]5[CH]6=[CH]2[Fe+2]56789%1043[CH]=%11[CH]%10=[CH]9[C-]8([CH]%117)[P]1(C%12%13CC%14CC(CC(C%14)C%12)C%13)C%15%16CC%17CC(CC(C%17)C%15)C%16
• InChI: InChI=1S/C25H34P.C13H22P.2ClH.Fe.Pd/c1-2-4-23(3-1)26(24-11-17-5-18(12-24)7-19(6-17)13-24)25-14-20-8-21(15-25)10-22(9-20)16-25;1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;;;;/h1-4,17-22H,5-16H2;7-10H,1-6H3;2*1H;;/q2*-1;;;2*+2/p-2
• InChI key: BJILVUSTVVKBGK-UHFFFAOYSA-L

설명

일반 설명

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

애플리케이션

(tBuMPhos)PdCl₂ is an unsymmetrical ferrocene-based phosphine ligand. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. Pd catalysts containing CyMPhos can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp²-Csp³ coupling. Demonstrated Csp²-Csp³ couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR₂)).

기타 정보

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp²–Csp³ Couplings

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable