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Merck
모든 사진(1)

주요 문서

931950

Sigma-Aldrich

Sodium perchlorate

anhydrous, ≥99.9% trace metals basis

동의어(들):

Sodium Perchlorate, Hyperchloric acid sodium salt

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About This Item

실험식(Hill 표기법):
ClNaO4
CAS Number:
Molecular Weight:
122.44
MDL number:
UNSPSC 코드:
12352302
NACRES:
NA.23
분석:
≥99.9% trace metals basis
Grade:
anhydrous
battery grade
양식:
powder
solubility:
H2O: 209 g/dL at 15 °C

Grade

anhydrous
battery grade

Quality Level

분석

≥99.9% trace metals basis

양식

powder

불순물

≤1000 ppm (trace metals analysis)

pH

6.0-8.0 (25 °C, 5%, aq.sol.)

mp

482 °C

solubility

H2O: 209 g/dL at 15 °C

음이온 미량물

chloride (Cl-): ≤30 ppm
sulfate (SO42-): ≤20 ppm

양이온 미량물

Fe: ≤5 ppm
K: ≤500 ppm

응용 분야

battery manufacturing

SMILES string

[Na+].[Cl](=O)(=O)(=O)[O-]

InChI

1S/ClHO4.Na/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1

InChI key

BAZAXWOYCMUHIX-UHFFFAOYSA-M

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일반 설명

Anhydrous sodium perchlorate is a white crystalline solid. It is hygroscopic and absorbs water to form its monohydrate. Anhydrous sodium perchlorate is highly soluble in water, and soluble in a range of polar organic solvents such as methanol, ethanol, acetone, carbonates (including ethylene carbonate, dimethyl carbonate, propylene carbonate, and diethyl carbonate), and ethers (including dimethoxyethane, tetrahydrofuran, and triethylene glycol dimethyl ether). It is insoluble in benzene, chloroform, and toluene.

애플리케이션

The major application of anhydrous sodium perchlorate is as an electrolyte in sodium-ion batteries. It is popular because of its solubility in ethers and carbonates, its wide electrochemical stability window (e.g. from 0 to 5 V vs Na+/Na in propylene carbonate, triglyme, or diethylcarbonate)[1], and its compatibility with a wide range of materials. It has been used in batteries with hard-carbon anodes[2], mesoporous carbon anodes[3], sodium cobalt oxide cathodes (NaxCoO2)[4], sodium vanadium oxide cathodes (NaxVO2)[5], titanium dioxide cathodes[6], and emerging materials like high-entropy layered oxide cathodes[7].

포장

10 g in glass bottle
25 g in glass bottle

픽토그램

Flame over circleHealth hazardExclamation mark

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Ox. Sol. 1 - STOT RE 2

표적 기관

Thyroid

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 1


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문서 라이브러리 방문

In search of an optimized electrolyte for Na-ion batteries
Ponrouch, A., et al.
Energy & Environmental Science, 5, 8572-8583 (2012)
Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries.
Komaba, S., et al.
Advances in Functional Materials, 21, 3859-3867 (2011)
Chenglong Zhao et al.
Angewandte Chemie (International ed. in English), 59(1), 264-269 (2019-10-18)
Material innovation on high-performance Na-ion cathodes and the corresponding understanding of structural chemistry still remain a challenge. Herein, we report a new concept of high-entropy strategy to design layered oxide cathodes for Na-ion batteries. An example of layered O3-type NaNi0.12
Gianluca Longoni et al.
Nano letters, 17(2), 992-1000 (2016-12-28)
Rechargeable sodium-ion batteries are becoming a viable alternative to lithium-based technology in energy storage strategies, due to the wide abundance of sodium raw material. In the past decade, this has generated a boom of research interest in such systems. Notwithstanding
Jia Ding et al.
ACS nano, 7(12), 11004-11015 (2013-11-07)
We demonstrate that peat moss, a wild plant that covers 3% of the earth's surface, serves as an ideal precursor to create sodium ion battery (NIB) anodes with some of the most attractive electrochemical properties ever reported for carbonaceous materials.

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