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Merck
모든 사진(1)

주요 문서

D122807

Sigma-Aldrich

1,2-Diiodoethane

99%

동의어(들):

Ethylene diiodide, Ethylene iodide

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About This Item

Linear Formula:
ICH2CH2I
CAS Number:
Molecular Weight:
281.86
Beilstein:
1730870
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

분석

99%

양식

powder or crystals

mp

80-82 °C (lit.)

density

2.132 g/mL at 25 °C (lit.)

저장 온도

2-8°C

SMILES string

ICCI

InChI

1S/C2H4I2/c3-1-2-4/h1-2H2

InChI key

GBBZLMLLFVFKJM-UHFFFAOYSA-N

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애플리케이션

1,2-Diiodoethane can be used:
  • To synthesize samarium(II) iodide-water complex (SmI2-H2O complex), a single-electron transfer reagent, to further synthesize 3-hydroxy carboxylic acids.
  • To synthesize derivatives of regioselective homopropargyl alcohols by using sonochemical Barbier-type reaction conditions.
  • As an iodine source and an effective reagent for the dehydroxy-iodination of alcohols.

픽토그램

Exclamation mark

신호어

Warning

유해 및 위험 성명서

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

dust mask type N95 (US), Eyeshields, Gloves


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문서 라이브러리 방문

이미 열람한 고객

Halogenation through Deoxygenation of Alcohols and Aldehydes.
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Organic Letters, 20(10), 3061-3064 (2018)
Synthesis of homopropargyl alcohols via sonochemical Barbier-type reaction.
Lee ASY, et al.
Tetrahedron Letters, 45(7), 1551-1553 (2004)
Michal Szostak et al.
Nature protocols, 7(5), 970-977 (2012-04-28)
The single-step synthesis of 3-hydroxy carboxylic acids from readily available Meldrum's acids involves a selective monoreduction using a SmI(2)-H(2)O complex to give products in high crude purity, and it represents a considerable advancement over other methods for the synthesis of
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