추천 제품
분석
97%
refractive index
n20/D 1.402 (lit.)
bp
155-160 °C (lit.)
density
0.876 g/mL at 25 °C (lit.)
SMILES string
CCOC(CC)(OCC)OCC
InChI
1S/C9H20O3/c1-5-9(10-6-2,11-7-3)12-8-4/h5-8H2,1-4H3
InChI key
FGWYWKIOMUZSQF-UHFFFAOYSA-N
유사한 제품을 찾으십니까? 방문 제품 비교 안내
애플리케이션
Triethyl orthopropionate is commonly used in the Claisen rearrangement to construct new C-C bonds. It can react with pyrrole and chloroacetic acid to form 1,1,1- [tri-(pyrrol-2-yl)]propane.
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2
Storage Class Code
3 - Flammable liquids
WGK
WGK 1
Flash Point (°F)
140.0 °F - closed cup
Flash Point (°C)
60 °C - closed cup
개인 보호 장비
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
시험 성적서(COA)
제품의 로트/배치 번호를 입력하여 시험 성적서(COA)을 검색하십시오. 로트 및 배치 번호는 제품 라벨에 있는 ‘로트’ 또는 ‘배치’라는 용어 뒤에서 찾을 수 있습니다.
이미 열람한 고객
Stereoselectivity in the ortho ester Claisen rearrangements of the E and Z isomers of. gamma.-(1, 3-dioxan-4-yl) allyl alcohols.
Tadano K, et al.
The Journal of Organic Chemistry, 55(7), 2108-2113 (1990)
Acyclic stereoselection. 44. Diastereoselectivity in the ortho ester Claisen rearrangement of chiral propargylic alcohols. Use of. beta.-allenic esters as chiral methylmalonaldehyde synthons.
Henderson M A and Heathcock C H
The Journal of Organic Chemistry, 53(20), 4736-4745 (1988)
Reactions between pyrrole and orthoesters: preparation of tri-(pyrrol-2-yl) alkanes.
Reese C B and Yan H
Tetrahedron Letters, 42(32), 5545-5547 (2001)
The Johnson-Claisen rearrangement of 3-hydroxy-2-methylenealkanenitriles: Stereoselective synthesis of functionalized trisubstituted alkenes.
Basavaiah D and Pandiaraju S
Tetrahedron Letters, 36(5), 757-758 (1995)
Claisen rearrangement of (Z)-3-deoxy-3-C-[(hydroxymethyl) methylene]-1, 2: 5, 6-di-O-isopropylidene-. alpha.-D-ribo-hexofuranose with triethyl orthopropionate.
Tadano K, et al.
The Journal of Organic Chemistry, 54(5), 1223-1227 (1989)
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