T67806

Triisopropyl phosphite

95%

• 동의어(들): Isopropyl phosphite, Tri-2-propyl phosphite, Triisopropoxyphosphine, Tris(isopropyl) phosphite
• Linear Formula: [(CH₃)₂CHO]₃P
• CAS Number: 116-17-6
• Molecular Weight: 208.24
• Beilstein: 1701528
• EC Number: 204-130-0
• MDL number: MFCD00008874
• UNSPSC 코드: 12352100
• PubChem Substance ID: 24900404
• NACRES: NA.22

속성

• vapor pressure: <2 mmHg ( 20 °C)
• Quality Level: 200
• 분석: 95%
• refractive index: n20/D 1.411 (lit.)
• bp: 63-64 °C/11 mmHg (lit.)
• density: 0.844 g/mL at 25 °C (lit.)
• SMILES string: CC(C)OP(OC(C)C)OC(C)C
• InChI: 1S/C9H21O3P/c1-7(2)10-13(11-8(3)4)12-9(5)6/h7-9H,1-6H3
• InChI key: SJHCUXCOGGKFAI-UHFFFAOYSA-N

설명

애플리케이션

Triisopropyl phosphite can be used as a reactant:

• With Ru-based indenylidene complexes to form 1^st generation complexes for metathesis reactions.
• In Perkow-type reaction to synthesize compounds containing polarized carbon-carbon double bonds.
• For the synthesis of phosphonohydrazines by reacting with arylamines and isoamyl nitrite.

It can also be used as an alternative to triphenylphosphine in Mitsunobu reaction to facilitate the isolation of products.

안전성 정보

• 픽토그램: GHS06
• 신호어: Danger
• 유해 및 위험 성명서: H301,H315
• 예방조치 성명서: P301 + P310 + P330 - P302 + P352
• Hazard Classifications: Acute Tox. 3 Oral - Skin Irrit. 2
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flash Point (°F): 154.4 °F - closed cup
• Flash Point (°C): 68 °C - closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter