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Merck
모든 사진(1)

주요 문서

11291

Sigma-Aldrich

1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide

≥97.0% (NMR)

동의어(들):

EMIM BTI, EMIM TFSI, EMIMIm

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About This Item

실험식(Hill 표기법):
C8H11F6N3O4S2
CAS Number:
Molecular Weight:
391.31
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

분석

≥97.0% (NMR)

양식

liquid

불순물

<0.5% water

mp

≥−15 °C (lit.)

작용기

fluoro

SMILES string

CCn1cc[n+](C)c1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F

InChI

1S/C6H11N2.C2F6NO4S2/c1-3-8-5-4-7(2)6-8;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h4-6H,3H2,1-2H3;/q+1;-1

InChI key

LRESCJAINPKJTO-UHFFFAOYSA-N

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일반 설명

1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide [EMIM][N(Tf)2] is a room temperature ionic liquid (RTIL). ([EMIM][N(Tf)2]) as a non-aqueous solvent, is advantageous over traditional aprotic polar organic solvents in electrochemical investigation of electroactive species since it has low vapor pressure, high thermal stability, good conductivity and a wide electrochemical window. [EMIM][N(Tf)2] shows good solubility in CO2.

애플리케이션

[EMIM][N(Tf)2] may be used as a green solvent for the synthesis of zinc oxide (ZnO) nanoparticles under microwave conditions. It is useful in reactions which need a solvent with high CO2 solubility.

물리적 형태

fluorinated, hydrophobic ionic liquid

기타 정보

Enantioselective reactions in ionic liquids

법적 정보

Product protected by U.S. Patent 5,827,602 assigned to Covalent Associates, Inc. Woburn, Ma, USA

픽토그램

Skull and crossbones

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 3 Oral

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 1

개인 보호 장비

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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문서 라이브러리 방문

Liquid structure of room-temperature ionic liquid, 1-ethyl-3-methylimidazolium bis-(trifluoromethanesulfonyl) imide.
Fujii K, et al.
The Journal of Physical Chemistry B, 112(14), 4329-4336 (2008)
Thermodynamic properties of 1-ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide
Safarov, Javid, et al.
Journal of Chemical and Engineering Data, 56.1, 106-112 (2010)
Surfactant aggregation within room-temperature ionic liquid 1-ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide
Fletcher, Kristin A., and Siddharth Pandey
Langmuir, 20.1, 33-36 (2004)
Liquid? liquid equilibria in binary mixtures containing substituted benzenes with ionic liquid 1-ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide
Shiflett, Mark B., and Anne Marie S. Niehaus
Journal of Chemical and Engineering Data, 55.1, 346-353 (2009)
Solubility of carbon dioxide in the ionic liquid 1-ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide.
Schilderman AM, et al
Fluid Phase Equilibria, 260(1), 19-22 (2007)

문서

Ionic Liquids serve as non-aqueous electrolytes in electrochemical applications, valued for their conductivity and stability.

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