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Merck
모든 사진(1)

주요 문서

32766

Supelco

Tembotrione

PESTANAL®, analytical standard

동의어(들):

2-{2-Chloro-4-(methylsulfonyl)-3-[(2,2,2-trifluoroethoxy)methyl]benzoyl}-1,3-cyclohexanedione, 2-{2-Chloro-4-mesyl-3-[(2,2,2-trifluoroethoxy)methyl]benzoyl}cyclohexane-1,3-dione

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About This Item

실험식(Hill 표기법):
C17H16ClF3O6S
CAS Number:
Molecular Weight:
440.82
MDL number:
UNSPSC 코드:
41116107
PubChem Substance ID:
NACRES:
NA.24

Grade

analytical standard

Quality Level

제품 라인

PESTANAL®

유통기한

limited shelf life, expiry date on the label

기술

HPLC: suitable
gas chromatography (GC): suitable

응용 분야

agriculture
environmental

형식

neat

SMILES string

CS(=O)(=O)c1ccc(c(Cl)c1COCC(F)(F)F)C(=O)C2C(=O)CCCC2=O

InChI

1S/C17H16ClF3O6S/c1-28(25,26)13-6-5-9(15(18)10(13)7-27-8-17(19,20)21)16(24)14-11(22)3-2-4-12(14)23/h5-6,14H,2-4,7-8H2,1H3

InChI key

IUQAXCIUEPFPSF-UHFFFAOYSA-N

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일반 설명

Tembotrione is a member of β-triketone family of herbicides that is utilized for grass and broadleaf weed control during early to mid-post-emergence of field corn.

애플리케이션

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Tembotrione may be used as a reference standard for the determination of tembotrione in tomato by quick, easy, cheap, effective, rugged and safe (QuEchERS) extraction method and dispersive liquid-liquid microextraction (DLLME) followed by analysis using high performance liquid chromatography (HPLC) with diode array detection (DAD), in honeybees by modified QuEchERS extraction followed by analysis using LC and gas chromatography (GC) combined with tandem mass spectrometry (MS/MS), in food samples by ultra-high performance liquid chromatography (UHPLC) and quadrupole time-of-flight mass spectrometry (QTOFMS) with electrospray ionization and in plant tissues as well as water samples by DLLME, matrix solid-phase dispersion (MSPD), and solid-phase extraction (SPE) combined with HPLC-DAD.

법적 정보

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

픽토그램

Health hazardExclamation markEnvironment

신호어

Warning

유해 및 위험 성명서

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 2 - Skin Sens. 1 - STOT RE 2

표적 기관

Eyes,Liver,Kidney

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point (°F)

No data available

Flash Point (°C)

No data available

개인 보호 장비

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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시험 성적서(COA)

Lot/Batch Number

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문서 라이브러리 방문

Extraction procedures for the study of phytotoxicity and degradation processes of selected triketones in a water ecosystem.
Barchanska H, et al.
Environmental Science and Pollution Research International, 21(6), 4751-4758 (2014)
Vilena Kašuba et al.
Environmental science and pollution research international, 27(2), 1800-1807 (2019-11-24)
DNA damage in the liver and kidney cells of adult male Wistar rats was studied using the comet assay after a 28-day oral administration of tembotrione at doses of 0.0007, 0.0013 and 0.7 mg/kg b.w./day [AOEL (acceptable operator exposure level)
Screening of over 600 pesticides, veterinary drugs, food-packaging contaminants, mycotoxins, and other chemicals in food by ultra-high performance liquid chromatography quadrupole time-of-flight mass spectrometry (UHPLC-QTOFMS).
Perez-Ortega P, et al.
Food Analytical Methods, 10(5), 1216-1244 (2017)
Monopersulfate photocatalysis under 365 nm radiation. Direct oxidation and monopersulfate promoted photocatalysis of the herbicide tembotrione.
Solis RR, et al.
Journal of Environmental Management, 181, 385-394 (2016)
Anita Küpper et al.
Pest management science, 74(10), 2325-2334 (2017-11-07)
Resistance to the 4-hydroxyphenylpyruvate dioxygenase (HPPD)-inhibiting herbicide tembotrione in an Amaranthus palmeri population from Nebraska (NER) has previously been confirmed to be attributable to enhanced metabolism. The objective of this study was to identify and quantify the metabolites formed in

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