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Merck
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주요 문서

38292

Supelco

Diisopropylamine

analytical standard

동의어(들):

DIPA

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About This Item

Linear Formula:
(CH3)2CHNHCH(CH3)2
CAS Number:
Molecular Weight:
101.19
Beilstein:
605284
EC Number:
MDL number:
UNSPSC 코드:
41116107
PubChem Substance ID:
NACRES:
NA.24

Grade

analytical standard

Quality Level

vapor density

3.5 (vs air)

vapor pressure

50 mmHg ( 20 °C)

분석

≥99.5% (GC)

autoignition temp.

599 °F

유통기한

limited shelf life, expiry date on the label

expl. lim.

8.5 %

기술

HPLC: suitable
gas chromatography (GC): suitable

refractive index

n20/D 1.392 (lit.)
n20/D 1.392

bp

84 °C (lit.)

mp

−61 °C (lit.)

solubility

H2O: soluble 110 g/L at 25 °C (completely)

density

0.722 g/mL at 25 °C (lit.)

응용 분야

environmental

형식

neat

SMILES string

CC(C)NC(C)C

InChI

1S/C6H15N/c1-5(2)7-6(3)4/h5-7H,1-4H3

InChI key

UAOMVDZJSHZZME-UHFFFAOYSA-N

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일반 설명

Diisopropylamine, an aliphatic secondary amine, is a well-known precursor of lithium diisopropylamide (LDA), which is a hindered, strong, non-nucleophilic base utilized in various organic reactions.

애플리케이션

Diisopropylamine may be used as an analytical standard for the determination of the analyte in air samples by high performance liquid chromatography (HPLC) technique.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

추천 제품

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

픽토그램

FlameSkull and crossbonesCorrosion

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point (°F)

7.8 °F - closed cup

Flash Point (°C)

-13.45 °C - closed cup

개인 보호 장비

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


가장 최신 버전 중 하나를 선택하세요:

시험 성적서(COA)

Lot/Batch Number

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문서 라이브러리 방문

Determination of aliphatic primary and secondary amines and polyamines in air by high-performance liquid chromatography
Simon P and Lemacon C
Analytical Chemistry, 59(3), 480-484 (1987)
Reductions of. alpha.-substituted ketones by lithium diisopropylamide
Kowalski C, et al.
The Journal of Organic Chemistry, 43(13), 2601-2608 (1978)
Songping Liao et al.
Journal of the American Chemical Society, 125(49), 15114-15127 (2003-12-05)
Lithium diisopropylamide-mediated lithiations of N-alkyl ketimines derived from cyclohexanones reveal that simple substitutions on the N-alkyl side chain and the 2-position of the cyclohexyl moiety afford a 60,000-fold range of rates. Detailed rate studies implicate monosolvated monomers at the rate-limiting
Antonio Ramirez et al.
Journal of the American Chemical Society, 128(31), 10326-10336 (2006-08-03)
Structural, kinetic, and computational studies reveal the mechanistic complexities of a lithium diisopropylamide (LDA)-mediated ester enolization. Hemilabile amino ether MeOCH2CH2NMe2, binding as an eta1 (ether-bound) ligand in the reactant and as an eta2 (chelating) ligand in the transition structure, accelerates
Kanwal Jit Singh et al.
Journal of the American Chemical Society, 128(42), 13753-13760 (2006-10-19)
Structural and mechanistic studies of the lithium diisopropylamide (LDA)-mediated anionic Fries rearrangements of aryl carbamates are described. Substituents at the meta position of the arene (H, OMe, F) and the dialkylamino moiety of the carbamate (Me(2)N, Et(2)N, and i-Pr(2)N) markedly

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