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Merck
모든 사진(1)

주요 문서

93335

Sigma-Aldrich

Europium(III) tris[3-(heptafluoropropylhydroxymethylene)-d-camphorate]

puriss. p.a., for NMR spectroscopy

동의어(들):

Eu(hfc)3, Tris[3-(heptafluoropropylhydroxymethylene)-d-camphorato]europium(III)

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About This Item

실험식(Hill 표기법):
C42H42EuF21O6
CAS Number:
Molecular Weight:
1193.71
EC Number:
MDL number:
UNSPSC 코드:
12352115
PubChem Substance ID:
NACRES:
NA.22

Grade

for NMR spectroscopy

Quality Level

grade

puriss. p.a.

양식

powder

mp

~160 °C (lit.)

작용기

fluoro
ketone

저장 온도

2-8°C

SMILES string

CC1(C)C2CC[C@@]1(C)C(=O)C2=C(O[Eu](OC(=C3C4CC[C@@](C)(C3=O)C4(C)C)C(F)(F)C(F)(F)C(F)(F)F)OC(=C5C6CC[C@@](C)(C5=O)C6(C)C)C(F)(F)C(F)(F)C(F)(F)F)C(F)(F)C(F)(F)C(F)(F)F

InChI

1S/3C14H15F7O2.Eu/c3*1-10(2)6-4-5-11(10,3)8(22)7(6)9(23)12(15,16)13(17,18)14(19,20)21;/h3*6,23H,4-5H2,1-3H3;/q;;;+3/p-3/b3*9-7+;/t3*6-,11+;/m111./s1

InChI key

VGLKHVQPWGFXEG-PSMAIOHISA-K

애플리케이션

It may be used as the NMR shift reagent in the 1H NMR analysis to determine the following:
  • Enantiomeric purities of the precursors of trisporic acids A, B and related products.
  • Optical purity of racemic 6,7-dichloro-5-methoxy-2-methyl-2-phenyl-1 indanone.
  • Epimeric purity of 4-methylsulfinylbutylglucosinolate.

포장

Bottomless glass bottle. Contents are inside inserted fused cone.

기타 정보

Chiral shift reagent for the determination of enantiomer ratios by NMR ; Measurements in polar solvents; For use as a Lanthanide shift reagent

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Gloves, type N95 (US)


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시험 성적서(COA)

Lot/Batch Number

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문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

M. Calmes et al.
Tetrahedron, 43, 2285-2285 (1987)
Enantioselective synthesis of the white key intermediate for the synthesis of trisporic acids.
Bacigaluppo JA, et al.
Tetrahedron Asymmetry, 5(10), 1877-1880 (1994)
Determination of the absolute configuration of the glucosinolate methyl sulfoxide group reveals a stereospecific biosynthesis of the side chain.
Vergara F, et al.
Phytochemistry, 69(15), 2737-2742 (2008)
Optical purity determination and 1H-NMR spectral simplification with lanthanide shift reagents-VIII. An indacrinone precursor, 6, 7-dichloro-5-methoxy-2-methyl-2-phenyl-1-indanone.
Hatzis A and Rothchild R.
Journal of Pharmaceutical and Biomedical Analysis, 4(4), 443-449 (1986)
L.M. Sweeting et al.
The Journal of Organic Chemistry, 52, 2273-2273 (1987)

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