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애플리케이션
Potassium fluoride dihydrate may be used in the following processes:
- As a source of active fluoride ion when used in combination with tetra-n-butylammonium chloride.
- To generate tetrabutylammonium fluoride in situ by reacting with tetrabutylammonium hydrogensulfate, which can catalyze the esterification of carboxylic acids with alkyl halides and ring-opening of aziridines.
- In combination with chlorotrimethylsilane for the desilylation of O-tert-butyldimethylsilyl ethers.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral
Storage Class Code
13 - Non Combustible Solids
WGK
WGK 1
이미 열람한 고객
Chromatographia, 28, 179-179 (1989)
Convenient source of 'naked'fluoride: tetra-n-butylammonium chloride and potassium fluoride dihydrate.
Journal of the Chemical Society. Chemical Communications, 11, 514-515 (1979)
Esterification of carboxylic acids catalyzed by in situ generated tetraalkylammonium fluorides
Tetrahedron Letters, 42(52), 9245-9248 (2001)
A Mild and Efficient Desilylation of O-tert-Butyldimethylsilyl Ethers Mediated by Chlorotrimethylsilane and Potassium Fluoride Dihydrate in Acetonitrile
Synlett, 2006(08), 1165-1168 (2006)
Efficient halogenation of unsaturated organoaluminum compounds with sulfonyl halides.
Russ. J. Org. Chem., 49(3), 321-326 (2013)
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