25059

Potassium acetate

puriss., meets analytical specification of Ph. Eur., BP, E261, 99-101%

• Linear Formula: CH₃COOK
• CAS Number: 127-08-2
• Molecular Weight: 98.14
• Beilstein: 3595449
• EC Number: 204-822-2
• MDL number: MFCD00012458
• UNSPSC 코드: 12352302
• PubChem Substance ID: 329752771
• NACRES: NA.21

속성

• vapor pressure: <0.0000001 hPa ( 25 °C)
• Quality Level: 200
• grade: puriss.
• 분석: 99-101%
• 형태: crystalline
• 품질: meets analytical specification of Ph. Eur., BP, E261
• 불순물: residual solvents, complies; ≤0.0004% heavy metals (as Pb); ≤0.05% KMnO₄ red. matter (as HCOOH)
• 손실: ≤1% loss on drying, 150 °C, 2 h
• pH: 7.5-9 (20 °C, 5%)
• density: 1.57 g/cm³ at 25 °C (lit.)
• 음이온 미량물: chloride (Cl^-): ≤50 mg/kg; sulfate (SO₄^2-): ≤100 mg/kg
• 양이온 미량물: Al: ≤1 mg/kg; As: ≤2 mg/kg; Ca: ≤50 mg/kg; Cu: ≤4 mg/kg; Fe: ≤10 mg/kg; Mg: ≤30 mg/kg; Na: ≤5000 mg/kg; Pb: ≤4 mg/kg; Zn: ≤10 mg/kg
• SMILES string: [K+].CC([O-])=O
• InChI: 1S/C2H4O2.K/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1
• InChI key: SCVFZCLFOSHCOH-UHFFFAOYSA-M

설명

일반 설명

Potassium acetate is a hygroscopic potassium salt. It can be prepared by the neutralization of acetic acid with potassium hydroxide or potassium carbonate. It can be used as nucleophilic catalyst for polymerization and addition reactions, source of acetate anion in substitution and addition reaction. It can be used as a base and promoter in various organic reactions.

애플리케이션

Potassium acetate is used as a catalyst:

• In the preparation of 2-hexadecylfuran from furfuraldehyde and palmitic anhydride.
• Potassium acetate can be used as a base:,In Lossen rearrangement of hydroxamic acids to carbamic acids.
• In E₂ elimination reactions.
• In the formation of lactones from alkoxyamide substrates.

Potassium acetate is also used as a promoter:

• In the borylation of aryl chlorides with bis(pinacolato)diboron in presence of palladium catalyst.
• In the β-boration of α, β-unsaturated ketones.

안전성 정보

• Storage Class Code: 13 - Non Combustible Solids
• WGK: WGK 1
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable