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Key Documents

402990

Sigma-Aldrich

Iodine monochloride

ACS reagent, 1.10±0.1 I/Cl ratio basis

동의어(들):

Chloroiodide

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About This Item

Linear Formula:
ICl
CAS Number:
Molecular Weight:
162.36
EC Number:
MDL number:
UNSPSC 코드:
12352300
PubChem Substance ID:
NACRES:
NB.24

Grade

ACS reagent

형태

solid or liquid

불순물

≤0.005% insolubles

bp

97.4 °C (lit.)

solubility

acetic acid: soluble(lit.)
acetone: soluble(lit.)
alcohol: soluble(lit.)
carbon disulfide: soluble(lit.)

density

3.24 g/mL at 25 °C (lit.)

저장 온도

2-8°C

SMILES string

ClI

InChI

1S/ClI/c1-2

InChI key

QZRGKCOWNLSUDK-UHFFFAOYSA-N

유사한 제품을 찾으십니까? 방문 제품 비교 안내

일반 설명

Iodine monochloride is an interhalogen compound. It forms various complexes with ethyl, isopropyl and t-butylbenzenes. Equilibrium constants for the formation of these complexes have been evaluated. It affords electrically conducting solution on dissolution in polar solvents. Its reaction with thymidine, 3-mono- and 3,3′,5′-trialkylsubstitued thymidine showed that it helps in deglycosylation, anomerization and isomerization of thymidine.

애플리케이션

Iodine monochloride (ICl) may be employed for the halogenation of methoxy and dimethoxybenzenes. It may be used for the synthesis of flavones.
Iodine monochloride may be used in the synthesis of the following:
  • 2-(4-haloisoquinolin-1-yl)ethanol derivatives
  • 5-iodosalicylaldehydes
  • 5-aryl-6-iodo-8-phenylpyrazolo[1,5-c]-1,2,4-triazolo[4,3-a]pyrimidines
  • (±)-1-cyclohexyl-4-iodo-3-methoxybutan-1-ol
  • (±)-4-Iodo-3-methoxy-1-phenylbutan-1-ol

픽토그램

CorrosionExclamation mark

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable


시험 성적서(COA)

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문서 라이브러리 방문

이미 열람한 고객

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Synthesis and Electrophilic Substitutions of Novel Pyrazolo [1, 5-c]-1, 2, 4-triazolo [4, 3-a] pyrimidines.
Atta KFM.
Molecules (Basel), 16(8), 7081-7096 (2011)
Brisbois RG, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2013)
Eric Stefan et al.
Tetrahedron, 69(36), 7706-7712 (2013-09-24)
Ether transfer methodology is capable of stereoselectively generating 1,3-diol mono- and diethers in good yield. Surprisingly, allylic and benzylic substrates provide none of the desired products when exposed to previously optimized conditions of iodine monochloride. Herein, second-generation activation conditions for
Three-Component Reactions of 2-Alkynylbenzaldoximes and α, β-Unsaturated Carbonyl Compounds with Bromine or Iodine Monochloride.
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Advanced Synthesis & Catalysis, 352(10), 1746-1751 (2010)

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