103748

2,3,4,5,6-Pentafluorobenzaldehyde

98%

• Synonym(s): Formylpentafluorobenzene, Pentafluorobenzaldehyde
• Linear Formula: C₆F₅CHO
• CAS Number: 653-37-2
• Molecular Weight: 196.07
• Beilstein/REAXYS Number: 1876550
• EC Number: 211-502-6
• MDL number: MFCD00003303
• UNSPSC Code: 12352100
• PubChem Substance ID: 24846620
• NACRES: NA.22

Properties

• Quality Level: 200
• assay: 98%
• refractive index: n20/D 1.45 (lit.)
• bp: 164-166 °C (lit.)
• mp: 24-28 °C (lit.)
• density: 1.588 g/mL at 25 °C (lit.)
• functional group: aldehyde; fluoro
• SMILES string: Fc1c(F)c(F)c(C=O)c(F)c1F
• InChI: 1S/C7HF5O/c8-3-2(1-13)4(9)6(11)7(12)5(3)10/h1H
• InChI key: QJXCFMJTJYCLFG-UHFFFAOYSA-N

Description

General description

2,3,4,5,6-Pentafluorobenzaldehyde reacts with 5-(aryl)dipyrromethanes to form a variety of meso-aryl [26]hexaphyrins.

Application

2,3,4,5,6-Pentafluorobenzaldehyde was used in the synthesis of novel, high molecular weight fluorinated aromatic polymers by superacid-catalyzed polyhydroxylation reaction of fluorinated carbonyl-containing compounds. 2,3,4,5,6-Pentafluorobenzaldehyde was used as derivatization reagent in a study to develop a sensitive method for the determination of primary amines in sewage sludge by headspace solid-phase microextraction and gas chromatography-tandem mass spectrometry.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H332,H335
• pcodes: P261 - P264 - P271 - P302 + P352 - P304 + P340 + P312 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Inhalation - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• wgk_germany: WGK 3
• flash_point_f: 170.6 °F - closed cup
• flash_point_c: 77 °C - closed cup
• ppe: dust mask type N95 (US), Eyeshields, Faceshields, Gloves