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Sigma-Aldrich

Ruthenium(III) chloride trihydrate

technical

Synonym(s):

Ruthenium trichloride trihydrate

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About This Item

Linear Formula:
RuCl3 · 3H2O
CAS Number:
13815-94-6
Molecular Weight:
261.47
MDL number:
MFCD00149845
UNSPSC Code:
12161600
PubChem Substance ID:
57646804
NACRES:
NA.22

grade

technical

Quality Level

100

form

solid

reaction suitability

core: ruthenium
reaction type: C-H Activation
reagent type: catalyst

SMILES string

O.O.O.Cl[Ru](Cl)Cl

InChI

1S/3ClH.3H2O.Ru/h3*1H;3*1H2;/q;;;;;;+3/p-3

InChI key

ZTWIEIFKPFJRLV-UHFFFAOYSA-K

Application

Ruthenium(III) chloride trihydrate can be used as a catalyst:
  • Precursor for the hydroamidation of terminalalkynes.
  • For the hydrolysis of 4-nitrobenzonitrile to 4-nitrobenzamide in the presence of 1,3,5-triaza-7-phosphaadamantane.
  • For the oxidation of thioethers to sulfones in the presence of sodium periodate and acetonitrile.

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Certificates of Analysis (COA)

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Sasaki, Y.; Dixneuf, P. H.
The Journal of Organic Chemistry, 52, 314-314 (1987)
Elif Demir et al.
Journal of colloid and interface science, 534, 704-710 (2018-10-01)
Ruthenium(0) nanoparticles were successfully prepared on the surface of ceria (Ru0/CeO2) and used as catalysts on glassy carbon electrode (GCE) in oxygen evolution reaction (OER) from water electrolysis at room temperature. Ru0/CeO2 on GCE exhibits high catalytic activity for OER
Zhiwei Jiang et al.
Chemistry, an Asian journal, 12(13), 1598-1604 (2017-05-04)
The biodiesel production process generates a significant amount of glycerol as a byproduct. A drive to add value has attracted worldwide attention, with the aim of improving the overall effectiveness and profitability of biodiesel production. Herein, we report hydroxyapatite (HAP)-supported
Tenaglia, A.; Terranova, E. et al.
Tetrahedron Letters, 32, 1169-1169 (1991)
Synthesis of Orthogonally N-Protected, C-4 Functionalized Cyclic Guanidines from L-Serine
Silva D, et al.
Synlett, 28, 815-818 (2017)
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