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140910

Sigma-Aldrich

Bathocuproine

greener alternative

96%

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Synonym(s):
2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline, BCP
Empirical Formula (Hill Notation):
C26H20N2
CAS Number:
Molecular Weight:
360.45
Beilstein/REAXYS Number:
306714
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.23

assay

96%

form

powder

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

mp

279-283 °C (lit.)

λmax

~280 nm in methanol

orbital energy

HOMO 7 eV 
LUMO 3.5 eV 

OLED device performance

ITO/CuPc/NPD/TCTA/mCP:FIrpic (6%)/BCP/LiF/Al

  • Color: blue
  • Max. EQE: 4.2 %

ITO/NPD/CBP:Ir(ppy)3/BCP/Alq3/Mg:Al
  • Color: green
  • Max. Luminance: 100000 Cd/m2
  • Max. EQE: 8 %
  • Turn-On Voltage: 4.3 V

ITO/NPD/TCTA/BCPO:Ir(piq)3 (7-8%)/BCP/Alq3/LiF/Al
  • Color: red
  • Max. Luminance: 24529 Cd/m2
  • Max. EQE: 17 %
  • Turn-On Voltage: 2.7 V

ITO/NPD/TCTA/BCPO:Ir(ppy)3 (7-8%)/BCP/Alq3/LiF/Al
  • Color: green
  • Max. Luminance: 207839 Cd/m2
  • Max. EQE: 21.6 %
  • Turn-On Voltage: 2.1 V

greener alternative category

SMILES string

Cc1cc(-c2ccccc2)c3ccc4c(cc(C)nc4c3n1)-c5ccccc5

InChI

1S/C26H20N2/c1-17-15-23(19-9-5-3-6-10-19)21-13-14-22-24(20-11-7-4-8-12-20)16-18(2)28-26(22)25(21)27-17/h3-16H,1-2H3

InChI key

STTGYIUESPWXOW-UHFFFAOYSA-N

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This Item
699152932663906980
vibrant-m

140910

Bathocuproine

vibrant-m

699152

Bathocuproine

vibrant-m

906980

PFN-Br

assay

96%

assay

99.99% trace metals basis

assay

≥99% (HPLC)

assay

-

form

powder

form

powder

form

-

form

solid

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

-

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

λmax

~280 nm in methanol

λmax

277 nm

λmax

277 nm

λmax

-

orbital energy

HOMO 7 eV 

orbital energy

HOMO 7 eV , LUMO 3.5 eV 

orbital energy

HOMO 6.4 eV , LUMO 2.9 eV 

orbital energy

-

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product belongs to Enabling category of greener alternatives thus aligns with "Design for energy efficency". Electron transport organic materials have the chemical functionality to transport electrons and are used as electron transport layer in OLED devices. Click here for more information.

Application

Bathocuproine can be used as an electron modificationlayer or interlayer between ETL(electron transport layer) in perovskite solarcells, which can be fabricated using the spin-coating deposition method or thevacuum thermal evaporation method. The addition of bathocuproine enhances thepower conversion efficiency of organic photovoltaic cells.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 4

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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