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148938

Sigma-Aldrich

2-Iodopropane

contains copper as stabilizer, 99%

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Synonym(s):
Isopropyl iodide
Linear Formula:
(CH3)2CHI
CAS Number:
Molecular Weight:
169.99
Beilstein/REAXYS Number:
1098244
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

99%

form

liquid

contains

copper as stabilizer

refractive index

n20/D 1.498 (lit.)

bp

88-90 °C (lit.)

mp

−90 °C (lit.)

density

1.703 g/mL at 25 °C (lit.)

SMILES string

CC(C)I

InChI

1S/C3H7I/c1-3(2)4/h3H,1-2H3

InChI key

FMKOJHQHASLBPH-UHFFFAOYSA-N

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1 of 4

This Item
238414614734342017
2-Iodopropane contains copper as stabilizer, 99%

148938

2-Iodopropane

1,3-Diiodopropane 99%, contains copper as stabilizer

238414

1,3-Diiodopropane

1-Iodopropane-d7 ≥98 atom % D, ≥99% (CP), contains copper as stabilizer

614734

1-Iodopropane-d7

Heptafluoro-2-iodopropane 98%

342017

Heptafluoro-2-iodopropane

Quality Level

200

Quality Level

-

Quality Level

-

Quality Level

-

form

liquid

form

liquid

form

-

form

liquid

refractive index

n20/D 1.498 (lit.)

refractive index

n20/D 1.642 (lit.)

refractive index

-

refractive index

n20/D 1.329 (lit.)

mp

−90 °C (lit.)

mp

-

mp

-101 °C (lit.)

mp

-

density

1.703 g/mL at 25 °C (lit.)

density

2.576 g/mL at 25 °C (lit.)

density

1.820 g/mL at 25 °C

density

2.08 g/mL at 25 °C (lit.)

General description

2-Iodopropane is an organ iodine compound. It is commonly used as a homolytic and heterolytic alkylating agent and in the preparation of the α-isopropoxymethylene blocking group. Additionally, it acts as an intermediator in the conversion of thiocarbonate to alkene.

Application

2-Iodopropane (Isopropyl iodide) was used to prepare butyric and isobutyric acid.

2-Iodopropane is used as an alkylating agent in the conversion of phenols, alcohols, oximes, carboxylic acids, and heteroatomic compounds (indoles, pyridines, purines, tetrazoles, pyrazoles, and amines) to give corresponding products.

pictograms

FlameExclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

107.6 °F - closed cup

flash_point_c

42 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Joe Rashan et al.
Journal of AOAC International, 86(4), 694-702 (2003-09-26)
An alternative liquid chromatographic (LC) method was developed and validated for the simultaneous determination of methoxyl and 2-hydroxypropoxyl substituents in hypromellose and hypromellose acetate succinate. The method uses the hydriodic acid cleavage reaction, catalyzed by adipic acid, of the substituted
Timur Coskun et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(21), 6840-6844 (2013-03-29)
Glycerol is converted to a mixture of butyric and isobutyric acid by rhodium- or iridium-catalysed carbonylation using HI as the co-catalyst. The initial reaction of glycerol with HI results in several intermediates that lead to isopropyl iodide, which upon carbonylation
John J Orlando et al.
The journal of physical chemistry. A, 109(30), 6659-6675 (2006-07-13)
The reaction of Cl atoms with iodoethane has been studied via a combination of laser flash photolysis/resonance fluorescence (LFP-RF), environmental chamber/Fourier transform (FT)IR, and quantum chemical techniques. Above 330 K, the flash photolysis data indicate that the reaction proceeds predominantly
W Kenealy et al.
Journal of bacteriology, 146(1), 133-140 (1981-04-01)
Iodopropane inhibited cell growth and methane production when Methanobacterium thermoautotrophicum, Methanobacterium formicicum, and Methanosarcina barkeri were cultured on H2-CO2. Iodopropane (40 microM) inhibited methanogenesis (30%) and growth (80%) when M. barkeri was cultured mixotrophically on H2-CO2-methanol. The addition of acetate
Development and validation of analytical procedure--control of residual 2-iodopropane in latanoprost.
Aleksandra Groman et al.
Acta poloniae pharmaceutica, 67(6), 673-676 (2011-01-15)

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