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204854

Sigma-Aldrich

Vanadium(V) oxide

greener alternative

99.9% trace metals basis

Synonym(s):

Divanadium pentaoxide, Divanadium pentoxide, Pentaoxodivanadium, Vandia

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About This Item

Linear Formula:
V2O5
CAS Number:
Molecular Weight:
181.88
EC Number:
MDL number:
UNSPSC Code:
12352303
eCl@ss:
38180404
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

99.9% trace metals basis

form

powder

composition

V2O5

reaction suitability

reagent type: catalyst
core: vanadium

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

690 °C (lit.)

density

3.35 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

greener alternative category

SMILES string

O=[V](=O)O[V](=O)=O

InChI

1S/5O.2V

InChI key

GNTDGMZSJNCJKK-UHFFFAOYSA-N

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here for more details.

Application

Selective ammoxidation catalysts for such reactions as conversion of toluene to benzonitrile or propylene to acrylonitrile were prepared by a sol-gel method from V2O5, Sb2O3 and high purity hydrogen peroxide. Preparation of new stabilized, oxide ion-conducting, bismuth vanadate phases by a microwave assisted method, fromV2O5, Bi2O3 and other solid oxides, was reported. These ceramics show promise in solid oxide fuel cells, water-vapor electrolyzers and oxygen sensors.

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - Carc. 1B - Lact. - Muta. 2 - Repr. 2 - STOT RE 1 Inhalation - STOT SE 3

target_organs

Respiratory system, Respiratory Tract

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Junkal Gutierrez et al.
ChemSusChem, 5(12), 2323-2327 (2012-10-13)
A bacterial cellulose mat was used as a template for the fabrication of conductive photoswitchable hybrid nanopaper by the incorporation of sol-gel synthesized vanadium nanoparticles. The resulting nanopaper, prepared through a green pathway, was able to photoinduce a reversible color
Yeon Seok Kim et al.
Applied biochemistry and biotechnology, 168(5), 1143-1152 (2012-09-06)
The bactericidal activity of TiO(2) nanoparticles under visible light is very important in regards to its practical applications. In this paper, we synthesized vanadium-pentoxide-loaded TiO(2) nanoparticles (V(2)O(5)-TiO(2)) using a chemical vapor condensation method, followed by the impregnation method, and characterized
Gongming Wang et al.
ACS nano, 6(11), 10296-10302 (2012-10-12)
Here we report a new strategy to improve the electrochemical stability of vanadium oxide electrodes for pseudocapacitors. Vanadium oxides are known to suffer from severe capacitance loss during charging/discharging cycling, due to chemical dissolution and ion intercalation/deintercalation-induced material pulverization. We
Heng Ji et al.
Nano letters, 12(6), 2988-2992 (2012-05-15)
Vanadium dioxide (VO(2)) is a strongly correlated transition metal oxide with a dramatic metal-insulator transition at 67 °C. Researchers have long been interested in manipulating this transition via the field effect. Here we report attempts to modulate this transition in
Thomas B Starr et al.
Regulatory toxicology and pharmacology : RTP, 64(1), 155-160 (2012-07-04)
The National Toxicology Program (NTP) chronic inhalation bioassay of vanadium pentoxide (V(2)O(5)) produced "clear" evidence of lung tumors in B6C3F1 mice, but only "some" and "equivocal" evidence in male and female F344/N rats, respectively. No significant pairwise differences or trends

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