MilliporeSigma
All Photos(4)

Documents

205877

Sigma-Aldrich

Palladium(II) bromide

99%

Sign Into View Organizational & Contract Pricing

Synonym(s):
Palladium dibromide, Palladous bromide
Empirical Formula (Hill Notation):
Br2Pd
CAS Number:
Molecular Weight:
266.23
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.23

Assay

99%

form

powder

reaction suitability

reagent type: catalyst
core: palladium

density

5.173 g/mL at 25 °C (lit.)

SMILES string

Br[Pd]Br

InChI

1S/2BrH.Pd/h2*1H;/q;;+2/p-2

InChI key

INIOZDBICVTGEO-UHFFFAOYSA-L

Looking for similar products? Visit Product Comparison Guide

Compare Similar Items

View Full Comparison

Show Differences

1 of 4

This Item
205885323373464678
Palladium(II) bromide 99%

Sigma-Aldrich

205877

Palladium(II) bromide

Palladium(II) iodide 97%

Sigma-Aldrich

464678

Palladium(II) iodide

form

powder

form

powder

form

powder

form

powder

density

5.173 g/mL at 25 °C (lit.)

density

4 g/mL at 25 °C (lit.)

density

4 g/mL at 25 °C (lit.)

density

6.003 g/mL at 25 °C (lit.)

Quality Level

100

Quality Level

200

Quality Level

100

Quality Level

100

reaction suitability

reagent type: catalyst
core: palladium

reaction suitability

-

reaction suitability

-

reaction suitability

reagent type: catalyst
core: palladium

General description

Palladium(II) bromide (PdBr2) is widely used as Pd(II) catalyst. PdBr2 can be prepared by reacting palladium metal with HNO3 and HBr. Electrosynthesis of PdBr2 from palladium metal and HBr has been reported.

Application

Palladium(II) bromide (PdBr2) has been used as a source of Pd(0) precatalyst in various coupling reactions. It was also employed as catalyst for the carbonylative Heck coupling reaction of aryl bromides and vinyl ethers.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Documents related to the products that you have purchased in the past have been gathered in the Document Library for your convenience.

Visit the Document Library

Difficulty Finding Your Product Or Lot/Batch Number?

Product numbers are combined with Pack Sizes/Quantity when displayed on the website (example: T1503-25G). Please make sure you enter ONLY the product number in the Product Number field (example: T1503).

Example:

T1503
Product Number
-
25G
Pack Size/Quantity

Additional examples:

705578-5MG-PW

PL860-CGA/SHF-1EA

MMYOMAG-74K-13

1000309185

enter as 1.000309185)

Having trouble? Feel free to contact Technical Service for assistance.

Lot and Batch Numbers can be found on a product's label following the words 'Lot' or 'Batch'.

Aldrich Products

  • For a lot number such as TO09019TO, enter it as 09019TO (without the first two letters 'TO').

  • For a lot number with a filling-code such as 05427ES-021, enter it as 05427ES (without the filling-code '-021').

  • For a lot number with a filling-code such as STBB0728K9, enter it as STBB0728 without the filling-code 'K9'.

Not Finding What You Are Looking For?

In some cases, a COA may not be available online. If your search was unable to find the COA you can request one.

Request COA

Customers Also Viewed

Johannes Schranck et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(16), 4827-4831 (2012-03-17)
Three COming together: The first carbonylative Heck coupling reaction of aryl bromides and vinyl ethers leading to 1-aryl-3-alkoxy-2-propen-1-ones has been established (see scheme). Based on this coupling methodology, a novel one-pot synthesis of aryl-substituted pyrazoles was also realized.
Palladium (II) Bromide.
Mahoney SJ, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2013)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service