211354

(R)-(−)-1-(9-Anthryl)-2,2,2-trifluoroethanol

≥98%

• Synonym(s): (R)-(−)-α-(Trifluoromethyl)anthracene-9-methanol, (R)-(−)-2,2,2-Trifluoro-1-(9-anthryl)ethanol
• Empirical Formula (Hill Notation): C₁₆H₁₁F₃O
• CAS Number: 53531-34-3
• Molecular Weight: 276.25
• Beilstein/REAXYS Number: 4695163
• EC Number: 258-611-5
• MDL number: MFCD00001260
• UNSPSC Code: 12352005
• PubChem Substance ID: 24852682
• NACRES: NA.22

Properties

• assay: ≥98%
• optical activity: [α]25/D −30°, c = 6.0 in chloroform
• optical purity: ee: 98% (HPLC)
• mp: 132-135 °C (lit.)
• SMILES string: O[C@H](c1c2ccccc2cc3ccccc13)C(F)(F)F
• InChI: 1S/C16H11F3O/c17-16(18,19)15(20)14-12-7-3-1-5-10(12)9-11-6-2-4-8-13(11)14/h1-9,15,20H/t15-/m1/s1
• InChI key: ICZHJFWIOPYQCA-OAHLLOKOSA-N

Description

Application

These enantiomerically pure (+)- and (−)-2,2,2-trifluoro-1-(9-anthryl)ethanols have been used for the NMR spectral determination of optical purity (and in some cases, absolute configuration) of a wide variety of sulfoxides, lactones, amines, sulfinate esters, oxaziridines and allenes.

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves