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225908

Sigma-Aldrich

Allylmagnesium chloride solution

2.0 M in THF

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Synonym(s):
Allyl magnesium chloride, Allylchloromagnesium, Allylmagnesium chloride, Chloro-2-propen-1-ylmagnesium
Linear Formula:
CH2=CHCH2MgCl
CAS Number:
Molecular Weight:
100.83
Beilstein/REAXYS Number:
3587316
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

reaction suitability

reaction type: Grignard Reaction

concentration

2.0 M in THF

density

0.995 g/mL at 25 °C

SMILES string

Cl[Mg]CC=C

InChI

1S/C3H5.ClH.Mg/c1-3-2;;/h3H,1-2H2;1H;/q;;+1/p-1

InChI key

PLYLAFITHJUEGX-UHFFFAOYSA-M

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1 of 4

This Item
324566419532225916
vibrant-m

225908

Allylmagnesium chloride solution

vibrant-m

324566

Octylmagnesium chloride solution

vibrant-m

225916

Benzylmagnesium chloride solution

density

0.995 g/mL at 25 °C

density

0.929 g/mL at 25 °C

density

0.915 g/mL at 25 °C

density

1.031 g/mL at 25 °C

Quality Level

100

Quality Level

200

Quality Level

100

Quality Level

100

concentration

2.0 M in THF

concentration

2.0 M in THF

concentration

0.5 M in THF

concentration

2.0 M in THF

General description

Allylmagnesiumchloride solution is an organic compound commonly used as a Grignard reagent inchemical reactions. It is used for the allylation of carbonyl compounds, such as aldehydes and ketones.

Application

Allylmagnesium chloride solution is used as a Grignard reagent in the preparation of:
  • Antipsychotic clopixol.
  • Polysilane–crown ether polymer (PSEC) using hexachloroplatinic acid as a catalyst.
  • 1,7-disubstituted-1,2,3,4-tetrahydroisoquinolinesfrom 3,4-dihydroisoquinoline.

signalword

Danger

Hazard Classifications

Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Water-react 1

supp_hazards

Storage Class

4.3 - Hazardous materials, which set free flammable gases upon contact with water

wgk_germany

WGK 1

flash_point_f

1.4 °F - closed cup - Solvent

flash_point_c

-17 °C - closed cup - Solvent

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Synthesis, In Vitro and In Silico Analysis of New Oleanolic Acid and Lupeol Derivatives against Leukemia Cell Lines: Involvement of the NF-?B Pathway
Fontana G, et al.
International Journal of Molecular Sciences, 6594-6594 (2022)
Tetrahedron Letters, 47, 9207-9207 (2006)

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