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Sigma-Aldrich

Vanadium(III) acetylacetonate

97%

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Synonym(s):
2,4-Pentanedione vanadium(III) derivative
Linear Formula:
V(C5H7O2)3
CAS Number:
Molecular Weight:
348.27
Beilstein:
4148970
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.23

Assay

97%

form

powder

reaction suitability

core: vanadium
reagent type: catalyst

mp

181-184 °C (lit.)

SMILES string

CC(=O)\C=C(\C)O[V](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

InChI

1S/3C5H8O2.V/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

InChI key

JTPOGAMSYINTGF-LNTINUHCSA-K

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1 of 4

This Item
338001C8785144920
form

powder

form

powder

form

powder

form

powder

mp

181-184 °C (lit.)

mp

-

mp

284-288 °C (dec.) (lit.)

mp

180-182 °C (dec.) (lit.), 180-190 °C (dec.)

reaction suitability

core: vanadium

reaction suitability

core: zirconium, reagent type: catalyst

reaction suitability

core: copper, reagent type: catalyst

reaction suitability

core: iron, reagent type: catalyst

Quality Level

100

Quality Level

200

Quality Level

200

Quality Level

200

Application

Vanadium(III) acetylacetonate can be used as a soluble catalyst, which acts as a redox mediator that allows effective oxidation of lithium peroxide for lithium-ion batteries. It can also be used as source material for the preparation of vanadium dioxide films by chemical vapor deposition (CVD) technique.

Other Notes

Surface of material may turn green upon exposure to air/moisture.

Pictograms

Skull and crossbones

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Customers Also Viewed

Vanadium dioxide thin films prepared by chemical vapour deposition from vanadium (III) acetylacetonate
Maruyama, T and Ikuta, Y
Journal of materials science & technology, 28(18), 5073-5078 (1993)
Vanadium (III) Acetylacetonate as an Efficient Soluble Catalyst for Lithium-Oxygen Batteries
Zhao Q, et al.
Angewandte Chemie (International Edition in English), 131(36), 12683-12687 (2019)

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