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237965

Sigma-Aldrich

Lithium fluoride

greener alternative

powder, -300 mesh

Synonym(s):

Fluorolithium

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About This Item

Linear Formula:
LiF
CAS Number:
Molecular Weight:
25.94
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

form

powder

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

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particle size

-300 mesh

mp

845 °C (lit.)

density

2.64 g/mL at 25 °C (lit.)

greener alternative category

SMILES string

[Li+].[F-]

InChI

1S/FH.Li/h1H;/q;+1/p-1

InChI key

PQXKHYXIUOZZFA-UHFFFAOYSA-M

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here for more information.

Application

Lithium fluoride (LiF) can be used as a sintering aid that facilitates the etching of spinel particles for the degradation of magnesium aluminum spinel. It can be used in the preparation of carbon-iron LiF nanocomposite based electrode materials for lithium-ion batteries. It can also form thin interlayers on the counter electrode to enhance the fill factor and stabilize the high open-circuit voltages for polymer solar cells.

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Skull and crossbones

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Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

supp_hazards

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Effect of LiFmetal electrodes on the performance of plastic solar cells
Brabec CJ, et al.
Applied Physics Letters, 80(7), 1288-1290 (2002)
Degradation of magnesium aluminum spinel by lithium fluoride sintering aid
Villalobos GR, et al.
Journal of the American Ceramic Society. American Ceramic Society, 88(5), 1321-1322 (2005)
A ferrocene-based carbon-iron lithium fluoride nanocomposite as a stable electrode material in lithium batteries
Prakash R, et al.
Journal of Materials Chemistry, 20(10), 1871-1876 (2010)
Fluorescent detection of single tracks of alpha particles using lithium fluoride crystals
Bilski P and Marczewska B
Nuclear Instruments & Methods in Physics Research. Section B, Beam Interactions With Materials and Atoms, 392, 41-45 (2017)
X W Meng et al.
The journal of physical chemistry. B, 115(16), 4768-4773 (2011-04-06)
On the basis of molecular dynamics simulations, we investigate water permeation across a single-walled carbon nanotube (SWCNT) under the influence of four symmetrical half-rings, each having six LiF dipolar molecules. The flux remains almost fixed as the separation, R, between

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