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669431

Sigma-Aldrich

Lithium fluoride

Precipitated, 99.995%

Synonym(s):

Fluorolithium

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About This Item

Linear Formula:
LiF
CAS Number:
Molecular Weight:
25.94
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

99.995%

form

powder

impurities

≤55.0 ppm Trace Metal Analysis

mp

845 °C (lit.)

density

2.64 g/mL at 25 °C (lit.)

SMILES string

[Li+].[F-]

InChI

1S/FH.Li/h1H;/q;+1/p-1

InChI key

PQXKHYXIUOZZFA-UHFFFAOYSA-M

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General description

Lithium fluoride is an inorganic halide with good ionic conductivity, high refractive index, and high transmittance in the UV region. Owing to its unique properties, it is widely used in the field of optical and electronic devices, X-ray imaging, and dental materials.

Application

Lithium fluoride(LiF) can be used:
  • To fabricate an insulating layer in AC-driven organic light-emitting diodes(OLEDs). LiF provides excellent capacitance and high stability to the insulating layers in AC devices.
  • As a precursor to synthesize Eu2+/Ce3+ doped barium lithium fluoride phosphors by solvothermal method.
  • To fabricate LiF thin film coating on the lithium anodes to enhance their stability and coulombic efficiency.
  • As an additive to enrich and enhance the performance of solidelectrolyte interface(SEI) in Li metal batteries.

pictograms

Skull and crossbones

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

supp_hazards

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Alternating current driven organic light emitting diodes using lithium fluoride insulating layers
Shang-Yi Liu, et al.
Scientific Reports, 4, 7559-7559 (2014)
Solvothermal fabrication and luminescent properties of Eu2+/Ce3+ doped barium lithium fluoride
Guoxian ZHU, et al.
Journal of Rare Earths, 30, 985-989 (2012)
Novel ALD Chemistry Enabled Low-Temperature Synthesis of Lithium Fluoride Coatings for Durable Lithium Anodes
Lin Chen, et al.
ACS Applied Materials & Interfaces, 10, 26972-26981 (2018)
The intrinsic behavior of lithium fluoride in solid electrolyte interphases on lithium
Mingfu He, et al.
Proceedings of the National Academy of Sciences, 117, 73-79 (2020)
Christian Bernhardsson et al.
Health physics, 103(6), 740-749 (2012-11-01)
Laboratory studies have shown that ordinary household salt (NaCl) exhibits several promising properties for retrospective dosimetry; e.g., a linear dose response and a low detection limit, down to a few mGy or even less. In an attempt to test NaCl

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