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289787

Sigma-Aldrich

Copper(II) hydroxide

technical grade

Synonym(s):

Cupric hydroxide

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About This Item

Linear Formula:
Cu(OH)2
CAS Number:
20427-59-2
Molecular Weight:
97.56
EC Number:
243-815-9
MDL number:
MFCD00010968
UNSPSC Code:
12352302
PubChem Substance ID:
24857213
NACRES:
NA.23

grade

technical grade

form

powder

contains

stabilizer

concentration

≥57.0% Cu (EDTA titration)

solubility

H2O: insoluble(lit.)
aqueous acid: slightly soluble(lit.)

application(s)

battery manufacturing

SMILES string

O[Cu]O

InChI

1S/Cu.2H2O/h;2*1H2/q+2;;/p-2

InChI key

JJLJMEJHUUYSSY-UHFFFAOYSA-L

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General description

The orthorhombic nature of copper hydroxide crystals was determined by X ray diffraction. Copper hydroxide can act as a heterogeneous catalyst in the selective oxidative cross coupling of terminal alkynes to yield their corresponding ynamides.

Application

Copper hydroxide based monoliths can be used in the synthesis of copper hydroxide-based monolithic xerogels. Potential applications of this metal organic frameworks (MOFs) include gas storage, separation, drug delivery, and biomedicine. Supported Cu(OH)x can be used as a catalyst for the aerobic cross dehydrogenative coupling of benzenethiols and cyclic amides to yield N-acylsulfenamides.

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Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

Storage Class

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCW7667
MKCV7615
MKCV0393
MKCV0475
MKCS8124

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Sonja Kosuta et al.
Journal of environmental quality, 31(3), 910-916 (2002-05-25)
The City of Montreal, Canada, evaluated the environmental impact and usefulness of in-ground copper (Cu)-treated baskets in controlling root growth of hardwood trees in nursery culture. Using baskets planted with 5-yr-old Norway maple (Acer platanoides L.) trees, the amount and
Heterogeneously catalyzed selective aerobic oxidative cross-coupling of terminal alkynes and amides with simple copper (ii) hydroxide.
Jin X, et al.
Chemical Communications (Cambridge, England), 48(41), 4974-4976 (2012)
Mechanically stable, hierarchically porous Cu 3 (btc) 2 (HKUST-1) monoliths via direct conversion of copper (ii) hydroxide-based monoliths.
Moitra N, et al.
Chemical Communications (Cambridge, England), 51(17), 3511-3514 (2015)
E S Vasetskiĭ et al.
Izvestiia Akademii nauk SSSR. Seriia biologicheskaia, (1)(1), 148-151 (1989-01-01)
A specific cosedimentation of proteins and their complexes with DNA at low temperature (M-band technique) has been demonstrated. Model experiments with reconstituted SV40 DNA-topoisomerase I and SV40 DNA-E. coli RNA polymerase complexes demonstrated the potential and capacities of the method.
Marie Simonin et al.
Ecological applications : a publication of the Ecological Society of America, 28(6), 1435-1449 (2018-06-26)
Despite the rapid rise in diversity and quantities of engineered nanomaterials produced, the impacts of these emerging contaminants on the structure and function of ecosystems have received little attention from ecologists. Moreover, little is known about how manufactured nanomaterials may
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