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302937

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Perfluoro(methylcyclohexane)

technical grade, 90%

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Synonym(s):
(Trifluoromethyl)undecafluorocyclohexane, Perfluoromethylcyclohexane
Linear Formula:
C6F11CF3
CAS Number:
Molecular Weight:
350.05
Beilstein/REAXYS Number:
1915981
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

grade

technical grade

Quality Level

assay

90%

form

liquid

refractive index

n17/D 1.285 (lit.)

bp

76 °C (lit.)

density

1.787 g/mL at 25 °C (lit.)

SMILES string

FC(F)(F)C1(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C1(F)F

InChI

1S/C7F14/c8-1(7(19,20)21)2(9,10)4(13,14)6(17,18)5(15,16)3(1,11)12

InChI key

QIROQPWSJUXOJC-UHFFFAOYSA-N

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This Item
282316372439337064
Perfluoro(methylcyclohexane) technical grade, 90%

302937

Perfluoro(methylcyclohexane)

Perfluoro-1,3-dimethylcyclohexane technical grade, 80%

282316

Perfluoro-1,3-dimethylcyclohexane

(Trifluoromethoxy)benzene 99%

337064

(Trifluoromethoxy)benzene

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

bp

76 °C (lit.)

bp

101-102 °C (lit.)

bp

137-160 °C (lit.)

bp

102 °C (lit.)

density

1.787 g/mL at 25 °C (lit.)

density

1.828 g/mL at 25 °C (lit.)

density

1.95 g/mL at 25 °C (lit.)

density

1.226 g/mL at 25 °C (lit.)

form

liquid

form

liquid

form

liquid

form

liquid

refractive index

n17/D 1.285 (lit.)

refractive index

n20/D 1.3 (lit.)

refractive index

n20/D 1.317 (lit.)

refractive index

n20/D 1.406 (lit.)

General description

Mixtures of chloroform and perfluoro(methylcyclohexane) can be used as solvents for "fluorous" biphase reactions. Gas-phase structure of perfluoro(methylcyclohexane) was investigated.

Application

Perfluoro(methylcyclohexane) can be used as:
  • A reactant to synthesize perfluoro-2-methylcyclohex-1-enolate by photochemical reaction with tetrabutylammonium iodide in water.
  • A fluorous solvent to synthesize polynorbornene via ring-opening metathesis polymerization (ROMP) of norbornene using fluorous Grubbs′ second-generation catalyst.

It can also be used as a solvent to investigate fluorophilicity of a series of hydrocarbon and fluorocarbon-functionalized nicotinic acid esters.
Perfluoro(methylcyclohexane) was employed as solvent to investigate fluorophilicity of a series of hydrocarbon and fluorocarbon-functionalized nicotinic acid esters.

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves


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The technique of hydrophobic ion pairing was used to solubilize the lipase from Candida rugosa in a fluorinated solvent, perfluoromethylcyclohexane (PFMC), in complex with a perfluoropolyether (PFPE) surfactant, KDP 4606. The enzyme-surfactant complex was determined to have a hydrodynamic diameter
S S Yang et al.
Biology of the neonate, 87(1), 60-65 (2004-10-07)
To test the hypothesis that intrapulmonary perfluorochemical (PFC) liquid may induce hypothermia, and to compare the effects of internal (IC), external (EC), and combined cooling techniques (EC + IC), 14 juvenile rabbits were randomized to EC by a cold blanket
John T Gerig
Journal of the American Chemical Society, 127(25), 9277-9284 (2005-06-23)
Mixtures of chloroform and perfluoro(methylcyclohexane) can be used as solvents for "fluorous" biphase reactions since they exist as two separate phases at low temperature but become a single phase at higher temperatures. Intermolecular nuclear Overhauser effects have been used to

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