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Sigma-Aldrich

Poly(acrylic acid)

Synonym(s):

PAA

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About This Item

Linear Formula:
(C3H4O2)n
CAS Number:
9003-01-4
MDL number:
MFCD00084394
UNSPSC Code:
12162002
PubChem Substance ID:
24859410
NACRES:
NA.23

mol wt

72.06 g/mol

viscosity

≤2000 cP

transition temp

Tg 106 °C

storage temp.

2-8°C

InChI

1S/C3H4O2.Na/c1-2-3(4)5;/h2H,1H2,(H,4,5);/q;+1/p-1

InChI key

NNMHYFLPFNGQFZ-UHFFFAOYSA-M

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General description

Poly (acrylic acid) (PAA) is hygroscopic, brittle and colorless in nature with Tg at nearly 106oC. At temperatures above 200 to 250oC, it loses water and becomes an insoluble crosslinked polymer anhydride. Solubility of dried PAA in water increases with rise in temperatures. Concentrated solutions of PAA in water is thixotropic in nature.

Application

Applications of PAA may include:
  • to study solute diffusion in Polyvinyl alcohol/PAA copolymer hydrogel
  • synthesizing poly(N-isopropylacrylamide)-block-PAA copolymer which responds to both temperature and pH stimuli
  • in preparing block copolymer of oligo (methyl methacrylate)/PAA for micellar delivery of hydrophobic drugs
  • as thickening agent for adhesives.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Nan Liu et al.
Nanoscale, 11(14), 6794-6801 (2019-03-26)
Sodium gadolinium fluoride (NaGdF4) nanoparticles are promising candidates as T1 shortening magnetic resonance imaging (MRI) contrast agents due to the paramagnetic properties of the Gd3+ ion. Effects of size and surface modification of these nanoparticles on proton relaxation times have
T Inoue et al.
Journal of controlled release : official journal of the Controlled Release Society, 51(2-3), 221-229 (1998-08-01)
An AB block copolymer of oligo(methyl methacrylate) (oMMA) and poly(acrylic acid) (PAAc) has been synthesized. The block copolymer forms micelles in an aqueous medium, as confirmed by a fluorescence probe technique using pyrene. Doxorubicin hydrochloride was incorporated into the micelle
P L Zeeuwen et al.
The Journal of investigative dermatology, 116(5), 693-701 (2001-05-12)
Using serial analysis of gene expression on cultured human keratinocytes we found high expression levels of genes putatively involved in host protection and defense, such as proteinase inhibitors and antimicrobial proteins. One of these expressed genes was the recently discovered
A New Double-Responsive Block Copolymer Synthesized via RAFT Polymerization: Poly (N-isopropylacrylamide)-b lock-poly (acrylic acid)
Schili CM, et al.
Macromolecules, 37(21), 7861-7866 (2004)
Yanxia Wang et al.
International journal of pharmaceutics, 441(1-2), 170-180 (2012-12-15)
A novel galactose-decorated cross-linked micelles (cl-micelles) with ionic cores using cystamine (Cys) as a biodegradable cross-linker was prepared by using block ionomer complexes of poly(ethylene glycol)-b-poly(2-acryloxyethyl-galactose)-b-poly(acrylic acid) (PEG-b-PAEG-b-PAA) and Ca(2+) (PEG-b-PAEG-b-PAA cl-micelles/Cys). Doxorubicin (DOX) was successfully incorporated into the ionic
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