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345334

Sigma-Aldrich

Poly(tetrahydrofuran)

average Mn ~2,900

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Synonym(s):
α-Hydro-ω-hydroxypoly(oxy-1,4-butanediyl), Poly(1,4-butanediol), polyTHF
Linear Formula:
H(OCH2CH2CH2CH2)nOH
CAS Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

vapor pressure

<0.01 mmHg ( 25 °C)
<1 mmHg ( 20 °C)

Quality Level

form

solid

mol wt

average Mn ~2,900

mp

30-43 °C

density

0.97 g/mL at 25 °C

SMILES string

OCCCCO

InChI

1S/C8H18O2/c1-3-5-6-10-8(4-2)7-9/h8-9H,3-7H2,1-2H3/t8-/m0/s1

InChI key

BJZYYSAMLOBSDY-QMMMGPOBSA-N

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General description

Poly(tetrahydrofuran) (PTHF) is a polyether that can be prepared by the cationic polymerization of tetrahydrofuran in the presence of a variety of initiator systems.

Application

PTHF can be used in the preparation of soft segment polyurethane for a variety of applications. It can also be used in the surface modification of cellulose fibers which can further be used as reinforcing polymerix materials.

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral - STOT SE 3

target_organs

Respiratory system

wgk_germany

WGK 3

flash_point_f

>325.4 °F

flash_point_c

> 163 °C

ppe

dust mask type N95 (US), Eyeshields, Gloves


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Mass spectral analysis of low-temperature pyrolysis products from poly (tetrahydrofuran)
Lattimer RP
Journal of Analytical and Applied Pyrolysis, 57(1), 57-76 (2001)
Surface functionalization of cellulose by grafting oligoether chains
Bras J, et al.
Materials Chemistry and Physics, 120(2-3), 438-445 (2010)
Melting behavior of poly (tetrahydrofuran)-S and their blends
Tsuchiya M and Kojima T
Journal of Thermal Analysis and Calorimetry, 72(2), 651-655 (2003)
25. Polytetrahydrofuran
Sugar Series, 13, 186-204 (2000)
Jae Hyung Park et al.
Journal of biomaterials science. Polymer edition, 13(5), 527-542 (2002-08-17)
A multiblock copolymer composed of poly(ethylene oxide) (PEO) and poly(tetramethylene oxide) (PTMO) and which forms a physical hydrogel was blended with Pellethane, a commercial segmented polyurethane (SPU) developed for various biomedical devices, to provide a PEO-rich surface with improved stability.

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