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345830

Sigma-Aldrich

3-Bromo-2-methylpropene

97%

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Synonym(s):
Methallyl bromide, Methylallyl bromide
Linear Formula:
H2C=C(CH3)CH2Br
CAS Number:
Molecular Weight:
135.00
MDL number:
PubChem Substance ID:

Quality Level

assay

97%

form

liquid

impurities

0.1% hydroquinone

refractive index

n20/D 1.472 (lit.)

bp

94-95 °C (lit.)

density

1.339 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CC(=C)CBr

InChI

1S/C4H7Br/c1-4(2)3-5/h1,3H2,2H3

InChI key

USEGQJLHQSTGHW-UHFFFAOYSA-N

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1 of 4

This Item
156582C81217614556
3-Bromo-2-methylpropene 97%

345830

3-Bromo-2-methylpropene

1-Bromo-2-methylpropane 99%

156582

1-Bromo-2-methylpropane

3-Bromo-1-phenyl-1-propene 97%

C81217

3-Bromo-1-phenyl-1-propene

2-Bromo-2-methylpropane-d9 98 atom % D

614556

2-Bromo-2-methylpropane-d9

bp

94-95 °C (lit.)

bp

90-92 °C (lit.)

bp

103 °C/22 mmHg (lit.)

bp

72-74 °C (lit.)

density

1.339 g/mL at 25 °C (lit.)

density

1.26 g/mL at 20 °C (lit.)

density

1.332 g/mL at 25 °C (lit.)

density

1.295 g/mL at 25 °C

refractive index

n20/D 1.472 (lit.)

refractive index

n20/D 1.435 (lit.)

refractive index

n20/D 1.621 (lit.)

refractive index

-

form

liquid

form

liquid

form

solid

form

-

storage temp.

2-8°C

storage temp.

-

storage temp.

2-8°C

storage temp.

-

General description

Rotational isomerism in 3-bromo-2-methylpropene has been studied by IR spectroscopy.

Application

3-Bromo-2-methylpropene may be used:
  • in the synthesis of alkenyl imines
  • in the synthesis of 2-methylpropenyl (“methallyl”) complex, Cp*Os(η3-allyl)Br2
  • in a study of chiral phase transfer alkylation leading to (S)-α-alkylcysteines

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

44.6 °F - closed cup

flash_point_c

7 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Customers Also Viewed

Slide 1 of 7

1 of 7

Intramolecular "hydroiminiumation" of alkenes: application to the synthesis of conjugate acids of cyclic alkyl amino carbenes (CAACs).
Rodolphe Jazzar et al.
Angewandte Chemie (International ed. in English), 46(16), 2899-2902 (2007-03-14)
Synthesis of Hydride and Alkyl Compounds Containing the Cp* Os (η3-allyl) Fragment. Crystal Structures of Cp* Os (η3-C8H13) Br2 and [Cp* Os (η3-C4H7) Me (H2O)][BF4].
Mui HD, et al.
Organometallics, 18(17), 3264-3272 (1999)
Taek-Soo Kim et al.
The Journal of organic chemistry, 71(21), 8276-8278 (2006-10-10)
We reported efficient enantioselective synthetic methodologies for (R)-alpha-alkylcysteines and (S)-alpha-alkylcysteines. The phase-transfer catalytic alkylation of 2-phenyl-2-thiazoline-4-carboxylic acid tert-butyl ester and 2-o-biphenyl-2-thiazoline-4-carboxylic acid tert-butyl ester, in the presence of chiral catalysts (1 or 2), gave the corresponding alkylated products, which could
Rotational isomerism in 3-bromo, 2-methylpropene studied by ir spectroscopy.
Diallo AO.
Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy, 36(9), 799-803 (1980)

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