409030
Poly(diallyldimethylammonium chloride) solution
average Mw 400,000-500,000 (high molecular weight), 20 wt. % in H2O
Synonym(s):
PDADMAC
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About This Item
Linear Formula:
(C8H16ClN)n
CAS Number:
MDL number:
UNSPSC Code:
12162002
NACRES:
NA.23
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form
viscous liquid
mol wt
average Mw 400,000-500,000 (high molecular weight)
concentration
20 wt. % in H2O
refractive index
n20/D 1.37
viscosity
600-900 cP(25 °C)
density
1.04 g/mL at 25 °C
SMILES string
[Cl-].[N+](CC=C)(CC=C)(C)C
InChI
1S/C8H16N.ClH/c1-5-7-9(3,4)8-6-2;/h5-6H,1-2,7-8H2,3-4H3;1H/q+1;/p-1
InChI key
GQOKIYDTHHZSCJ-UHFFFAOYSA-M
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General description
Poly(diallyldimethylammonium chloride) is a water-soluble cationic polymer that can be prepared from diallyl dimethyl ammonium chloride via free radical polymerization.
It is a positively charged polyelectrolyte that finds application in various fields such as paper manufacturing, the mining industry, water treatment, protein immobilization, separation of biomolecules, removal of bacteria, flocculation of silica and latex particles, and nanocapsule shell formation.
It is a positively charged polyelectrolyte that finds application in various fields such as paper manufacturing, the mining industry, water treatment, protein immobilization, separation of biomolecules, removal of bacteria, flocculation of silica and latex particles, and nanocapsule shell formation.
Application
- Influence of ionic strength on poly(diallyldimethylammonium chloride) macromolecule conformations in electrolyte solutions: Studies the effect of ionic strength on the conformation of PDADMAC in electrolyte solutions. (Z Adamczyk et al., 2014).
- Comparison of permeability of poly(allylamine hydrochloride) and poly(diallyldimethylammonium chloride)/poly(4-styrenesulfonate) multilayer films: Examines permeability differences in multilayer films of PAH and PDADMAC/PSS. (M Elżbieciak-Wodka et al., 2015).
- Effect of small molecules on the phase behavior and coacervation of aqueous solutions of poly(diallyldimethylammonium chloride) and poly(sodium 4-styrene sulfonate): Investigates the impact of small molecules on the coacervation of PDADMAC and PSS. (S Huang et al., 2018).
- Dynamic surface elasticity of mixed poly(diallyldimethylammonium chloride)/sodium dodecyl sulfate/NaCl solutions: Analyzes the dynamic dilational surface elasticity of PDADMAC/SDS/NaCl mixtures. (VV Lyadinskaya et al., 2014).
Storage Class
13 - Non Combustible Solids
wgk_germany
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
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Shear thickening behavior of dilute poly(diallyl dimethyl ammonium chloride) aqueous solutions
Wen-Hong Liu, et al.
Polymer, 48, 4152-4165 (2007)
Lulu Han et al.
Biomaterials, 34(4), 975-984 (2012-11-07)
The directional cell migration plays a crucial role in a variety of physiological and pathological processes. It can be controlled by the gradient cues immobilized on the substrate. The poly(sodium 4-styrenesulfonate) (PSS)/poly(diallyldimethylammonium) chloride (PDADMAC) multilayers were post-treated in a gradient
Lokesh S Koodlur
Bioelectrochemistry (Amsterdam, Netherlands), 91, 21-27 (2013-01-22)
A self-assembled molecular film of a water-soluble cobalt tetrasulfophthalocyanine was deposited on a gold substrate premodified with poly(diallyldimethylammonium chloride). The process of layer-by-layer assembly on the gold substrate was characterized using UV-Vis, Raman spectroscopy, ellipsometry, contact angle measurements, atomic force
Cédric Amorosi et al.
Colloids and surfaces. B, Biointerfaces, 97, 124-131 (2012-05-23)
Compact and linearly growing polyelectrolyte multilayer films have been used to suppress desorption of drugs, nanoparticles or proteins from underlying polyelectrolyte multilayer films as well as to significantly change their mechanical properties. The polyelectrolyte based capping layers are however cumbersome
Lulu Han et al.
Journal of the Royal Society, Interface, 9(77), 3455-3468 (2012-08-17)
The cell migration plays a crucial role in a variety of physiological and pathological processes and can be regulated by the cell-substrate interactions. We found previously that the poly(sodium 4-styrenesulphonate) (PSS)/poly(diallyldimethylammonium) chloride (PDADMAC) multilayers post-treated in 1-5 M NaCl solutions
Articles
We present an article that discusses two applications in particular; first, using these layers as polyelectrolyte membranes to control permeability.
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