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Key Documents

411124

Sigma-Aldrich

Chlorodicyclohexylborane solution

1 M in hexanes

Synonym(s):

Dicyclohexylboron chloride, Dicyclohexylboryl chloride, Dicyclohexylchloroborane

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About This Item

Linear Formula:
(C6H11)2BCl
CAS Number:
Molecular Weight:
212.57
Beilstein/REAXYS Number:
3233942
MDL number:
UNSPSC Code:
12352106
PubChem Substance ID:
NACRES:
NA.22

form

liquid

Quality Level

reaction suitability

reagent type: reductant

concentration

1 M in hexanes

bp

68-69 °C

density

0.752 g/mL at 25 °C

SMILES string

ClB(C1CCCCC1)C2CCCCC2

InChI

1S/C12H22BCl/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h11-12H,1-10H2

Inchi Key

PBBOKJIYEZCTEH-UHFFFAOYSA-N

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Application

Reactant for:
  • Aldol addition reactions
  • Mukaiyama aldol addition
  • Microwave assisted ring closing metathesis reactions
  • C-alkylation of aromatic aldimines
  • Reversible ketone-ketone aldol reactions
  • Syn- and anti-stereoselective aldol reaction hexenone with aldehydes

signalword

Danger

Hazard Classifications

Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 1 Inhalation - STOT SE 3

target_organs

Central nervous system, Nervous system

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk_germany

WGK 3

flash_point_f

10.4 °F - closed cup

flash_point_c

-12 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


Certificates of Analysis (COA)

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