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406139

Sigma-Aldrich

Chlorodicyclohexylborane

98%

Synonym(s):

Dicyclohexylboron chloride, Dicyclohexylboryl chloride, Dicyclohexylchloroborane

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About This Item

Linear Formula:
(C6H11)2BCl
CAS Number:
Molecular Weight:
212.57
MDL number:
UNSPSC Code:
12352106
PubChem Substance ID:

Quality Level

assay

98%

form

liquid

reaction suitability

reagent type: reductant

bp

100-101 °C/1 mmHg (lit.)

density

0.97 g/mL at 25 °C (lit.)

SMILES string

ClB(C1CCCCC1)C2CCCCC2

InChI

1S/C12H22BCl/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h11-12H,1-10H2

InChI key

PBBOKJIYEZCTEH-UHFFFAOYSA-N

Related Categories

Application

A convenient reagent for regio- and stereoselective enolboration of ketones and other carbonyl derivatives.
Reactant for:
  • Aldol addition reactions
  • Mukaiyama aldol addition
  • Microwave assisted ring closing metathesis reactions
  • C-alkylation of aromatic aldimines
  • Reversible ketone-ketone aldol reactions
  • Syn- and anti-stereoselective aldol reaction hexenone with aldehydes

pictograms

FlameCorrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1B

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk_germany

WGK 3

flash_point_f

No data available

flash_point_c

No data available


Certificates of Analysis (COA)

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The Journal of Organic Chemistry, 57, 499-499 (1992)

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