417696

Zinc bis[bis(trimethylsilyl)amide]

97%

• Synonym(s): Bis[1,1,1-trimethyl-N-(trimethylsilyl)silanaminato]zinc, Bis[bis(trimethylsilyl)amido]zinc, Zinc bis(hexamethyldisilazide, 1,1,1,3,3,3-Hexamethyldisilazane zinc salt
• Linear Formula: [[(CH₃)₃Si]₂N]₂Zn
• CAS Number: 14760-26-0
• Molecular Weight: 386.16
• MDL number: MFCD01321225
• UNSPSC Code: 12161600
• PubChem Substance ID: 24866173
• NACRES: NA.22

Properties

• assay: 97%
• form: liquid
• reaction suitability: core: zinc; reagent type: catalyst
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 12.5 °C (lit.)
• density: 0.957 g/mL at 25 °C (lit.)
• greener alternative category: Aligned,
• SMILES string: C[Si](C)(C)N([Zn]N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C
• InChI: 1S/2C6H18NSi2.Zn/c2*1-8(2,3)7-9(4,5)6;/h2*1-6H3;/q2*-1;+2
• InChI key: ZCCUYQBZUVUONI-UHFFFAOYSA-N

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

• Cooperative effects of Schiff base binuclear zinc complexes on the synthesis of aliphatic and semi-aromatic polyesters.: This study explores the cooperative effects of binuclear zinc complexes in the synthesis of various polyesters, highlighting the potential of zinc bis[bis(trimethylsilyl)amide] in enhancing polymerization efficiency and selectivity (Santulli et al., 2023).


• Synthesis, solution dynamics and chemical vapour deposition of heteroleptic zinc complexes via ethyl and amide zinc thioureides.: The authors discuss the synthesis and dynamics of zinc complexes for chemical vapor deposition, emphasizing the role of zinc bis[bis(trimethylsilyl)amide] as a precursor in developing high-purity metalorganic films (Bhide et al., 2021).

Safety Information

• pictograms: GHS02,GHS05
• signalword: Danger
• hcodes: H261,H314
• pcodes: P223 - P231 + P232 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Skin Corr. 1B - Water-react 2
• Storage Class: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• wgk_germany: WGK 3
• flash_point_f: 105.8 °F - closed cup
• flash_point_c: 41 °C - closed cup
• ppe: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges