MilliporeSigma
All Photos(1)

Documents

430056

Sigma-Aldrich

Benzyltriphenylphosphonium bromide

96%

Sign Into View Organizational & Contract Pricing

Select a Size

Change View

Select a Size

Change View
Synonym(s):
(Phenylmethyl)triphenylphosphonium bromide, Bromo(benzyl)triphenylphosphorane, NSC 54813
Linear Formula:
C6H5CH2P(Br)(C6H5)3
CAS Number:
Molecular Weight:
433.32
Beilstein:
3599867
EC Number:
MDL number:
PubChem Substance ID:

Assay

96%

reaction suitability

reaction type: C-C Bond Formation

mp

295-298 °C (lit.)

SMILES string

[Br-].C(c1ccccc1)[P+](c2ccccc2)(c3ccccc3)c4ccccc4

InChI

1S/C25H22P.BrH/c1-5-13-22(14-6-1)21-26(23-15-7-2-8-16-23,24-17-9-3-10-18-24)25-19-11-4-12-20-25;/h1-20H,21H2;1H/q+1;/p-1

InChI key

WTEPWWCRWNCUNA-UHFFFAOYSA-M

Looking for similar products? Visit Product Comparison Guide

Related Categories

Compare Similar Items

View Full Comparison

Show Differences

1 of 4

This Item
157945B32807349720
reaction suitability

reaction type: C-C Bond Formation

reaction suitability

reaction type: C-C Bond Formation

reaction suitability

reaction type: C-C Bond Formation

reaction suitability

reaction type: C-C Bond Formation

mp

295-298 °C (lit.)

mp

204-207 °C (lit.)

mp

≥300 °C (lit.)

mp

244-247 °C (lit.)

Application

Reactant for:
  • Stereoselective azidolysis of vinyl epoxides
  • Enantioselective aziridination and Friedel-Crafts cyclization for asymmetric synthesis of dihydrexidine
  • Biomimetic iron(III) mediated oxidative dimerization for synthesis of benzoquinone parvistemin A
  • Enantioselective sytnhesis of syn-diarylheptanoids from D-glucose
  • Preparation of β-amyloid plaque ligands
  • Decarboxylative cyclopropanation

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Documents related to the products that you have purchased in the past have been gathered in the Document Library for your convenience.

Visit the Document Library

Difficulty Finding Your Product Or Lot/Batch Number?

Product numbers are combined with Pack Sizes/Quantity when displayed on the website (example: T1503-25G). Please make sure you enter ONLY the product number in the Product Number field (example: T1503).

Example:

T1503
Product Number
-
25G
Pack Size/Quantity

Additional examples:

705578-5MG-PW

PL860-CGA/SHF-1EA

MMYOMAG-74K-13

1000309185

enter as 1.000309185)

Having trouble? Feel free to contact Technical Service for assistance.

Lot and Batch Numbers can be found on a product's label following the words 'Lot' or 'Batch'.

Aldrich Products

  • For a lot number such as TO09019TO, enter it as 09019TO (without the first two letters 'TO').

  • For a lot number with a filling-code such as 05427ES-021, enter it as 05427ES (without the filling-code '-021').

  • For a lot number with a filling-code such as STBB0728K9, enter it as STBB0728 without the filling-code 'K9'.

Not Finding What You Are Looking For?

In some cases, a COA may not be available online. If your search was unable to find the COA you can request one.

Request COA

Customers Also Viewed

Slide 1 of 2

1 of 2

Benzyl bromide reagent grade, 98%

Sigma-Aldrich

B17905

Benzyl bromide

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service