510475

Bis(methylcyclopentadienyl)nickel(II)

97%

• Synonym(s): 1,1′-Dimethylnickelocene
• Linear Formula: Ni(C₅H₄CH₃)₂
• CAS Number: 1293-95-4
• Molecular Weight: 216.93
• MDL number: MFCD01863654
• UNSPSC Code: 12161600
• PubChem Substance ID: 24873505
• NACRES: NA.22

Properties

• assay: 97%
• form: liquid
• reaction suitability: core: nickel; reagent type: catalyst
• bp: 85-90 °C/1 mmHg (lit.)
• mp: 34-36 °C (lit.)
• storage temp.: 2-8°C
• SMILES string: [Ni].C[C]1[CH][CH][CH][CH]1.C[C]2[CH][CH][CH][CH]2
• InChI: 1S/2C6H7.Ni/c2*1-6-4-2-3-5-6;/h2*2-5H,1H3;
• InChI key: IHRNDXJDUYVDRB-UHFFFAOYSA-N

Description

Application

Reactant for synthesis of:

• Nickel sandwich complexes
• N-heterocyclic carbene complexes
• Functionally substituted monocyclopentadienyl compounds

Features and Benefits

Volatile OMCVD precursor for the controlled growth of nickel nanoparticles on silicon substrates. Possible uses for metallic nickel nanoparticles embedded on silicon include the manufacture of high-density storage media 9. Nickel oxide thin films are generated via OMCVD in the presence of O₂ or H₂O₂.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H302 + H312 + H332
• pcodes: P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
• Storage Class: 10 - Combustible liquids
• wgk_germany: WGK 3
• flash_point_f: 150.8 °F - closed cup
• flash_point_c: 66 °C - closed cup
• ppe: Eyeshields, Gloves, type N95 (US)