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51491

Sigma-Aldrich

Dibutyl sulfide

≥98.0% (GC)

Synonym(s):

1,1′-Thiobisbutane, Butyl sulfide, NSC 8460

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About This Item

Linear Formula:
CH3(CH2)3S(CH2)3CH3
CAS Number:
Molecular Weight:
146.29
Beilstein/REAXYS Number:
1732829
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

vapor density

5.07 (vs air)

vapor pressure

5.17 mmHg ( 37.7 °C)

assay

≥98.0% (GC)

refractive index

n20/D 1.452 (lit.)
n20/D 1.453

bp

188-189 °C (lit.)

mp

−76 °C (lit.)

density

0.838 g/mL at 25 °C (lit.)

SMILES string

CCCCSCCCC

InChI

1S/C8H18S/c1-3-5-7-9-8-6-4-2/h3-8H2,1-2H3

InChI key

HTIRHQRTDBPHNZ-UHFFFAOYSA-N

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General description

Butyl sulfide is a volatile organic sulfur compound that is used as an organic building block in chemical synthesis. It is used to prepare dibutyl sulfoxide (DBSO) via oxidation reaction. DBSO is used as a valuable organic solvent for the extraction of zirconium, palladium, platinum, and gold.

Application

  • Environmental Odor Diagnostics: Dibutyl sulfide was utilized in developing a diagnostic method for complex odor issues in micro-polluted source water, highlighting its role in environmental monitoring and pollution control (Guo et al., 2021).
  • Surface Chemistry Investigations: The adsorption and manipulation of dibutyl sulfide on copper surfaces were studied, providing insights into its interactions at the molecular level (Jensen et al., 2007).
  • Biosensor Development for Chemical Warfare Detection: Dibutyl sulfide′s effects were explored in the context of stand-off tissue-based biosensors for detecting chemical warfare agents, utilizing photosynthetic fluorescence induction, it is crucial in constructing the inertial forces of launching or dropping into suspected danger zones and, with encrypted telecommunication data transmission (Sanders et al., 2001).

wgk_germany

WGK 2

flash_point_f

170.6 °F

flash_point_c

77 °C

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Effect of irradiation intensity on rate and selectivity of photosensitized oxidation of dibutyl sulfide over C70 fullerene.
Arsentyev AV, et al.
High Energy Chemistry, 49(3), 167-172 (2015)
Revisiting the Zincke disulfide reaction for the post-polymerization functionalization of unsaturated polyolefins.
Dunst A, et al.
Polymer, 55(2), 5557-5560 (2014)
Dithiolane-Directed Tandem Oxidation/1, 2-Benzyl Migration of Tetramic Acids under Ambient Conditions.
Li Y, et al.
Advanced Synthesis & Catalysis, 354(9), 1712-1716 (2012)
Dibutyl sulfide: synthesis, Pd, Pt extraction and separation studies.
Lu P, et al.
Chinese Journal of Inorganic Chemistry / Wu Ji Hua Xue Xue Bao, 24(4), 520-526 (2008)
Electron transfer and singlet oxygen mechanisms in the photooxygenation of dibutyl sulfide and thioanisole in MeCN sensitized by N-methylquinolinium tetrafluoborate and 9, 10-dicyanoanthracene. The probable involvement of a thiadioxirane intermediate in electron transfer photooxygenations.
Baciocchi E, et al.
Journal of the American Chemical Society, 125(52), 16444-16454 (2003)

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