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2-Benzoylbenzoic acid methyl ester, Methyl o-benzoylbenzoate, o-(Methoxycarbonyl)benzophenone
C6H5COC6H4CO2CH3
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Quality Level
assay
97%
form
solid
mp
48-53 °C (lit.)
SMILES string
COC(=O)c1ccccc1C(=O)c2ccccc2
InChI
1S/C15H12O3/c1-18-15(17)13-10-6-5-9-12(13)14(16)11-7-3-2-4-8-11/h2-10H,1H3
InChI key
NQSMEZJWJJVYOI-UHFFFAOYSA-N
Related Categories
General description
Methyl-2-benzoylbenzoate is a 2-acylarylcarboxylate.
- It can undergo asymmetric transfer hydrogenation reaction in propanol in the presence of a Ruthenium catalyst.
- Methyl-2-benzoylbenzoate is formed as one of the reaction products during the reaction between methyl benzoate and lithium 2,2,6,6-tetramethylpiperidide (LiTMP) at -117°C.
- Methyl-2-benzoylbenzoate can be synthesized from the reaction between corresponding 2-substituted benzoic acid and thionyl chloride in methanol.
signalword
Warning
hcodes
pcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves
Certificates of Analysis (COA)
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Dipole stabilized carbanions. Reactions of benzoate esters with lithium 2, 2, 6, 6-tetramethylpiperidide.
The Journal of Organic Chemistry, 40(8), 1094-1098 (1975)
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The Journal of Organic Chemistry, 44(11), 1887-1888 (1979)
Stereoselective synthesis of 3-substituted phtalides via asymmetric transfer hydrogenation using well-defined ruthenium catalysts under neutral conditions.
Tetrahedron Letters, 42(10), 1899-1901 (2001)
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