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631507

Sigma-Aldrich

1,10-Phenanthrolin-5-amine

97%

Synonym(s):

(1,10)-Phenanthrolin-5-ylamine

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About This Item

Empirical Formula (Hill Notation):
C12H9N3
CAS Number:
54258-41-2
Molecular Weight:
195.22
MDL number:
MFCD00455733
UNSPSC Code:
12352100
PubChem Substance ID:
24882426
NACRES:
NA.22

assay

97%

mp

254-258 °C (lit.)

SMILES string

Nc1cc2cccnc2c3ncccc13

InChI

1S/C12H9N3/c13-10-7-8-3-1-5-14-11(8)12-9(10)4-2-6-15-12/h1-7H,13H2

InChI key

DKPSSMOJHLISJI-UHFFFAOYSA-N

Application

1,10-Phenanthrolin-5-amine can be used in the synthesis of bis-[1,10]phenanthrolin-5-yl-pyromellitic diimide (Bphen-PMD), which can find applications in organic light-emitting devices.

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Sens. 1

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCT9838
MKCT2026
MKCR3309
MKCP5738
MKCJ3957

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Siew San Tan et al.
Physical chemistry chemical physics : PCCP, 19(37), 25734-25745 (2017-09-16)
An absorbance-based sensor employing ruthenium bipyridyl with a phenanthroline-fused benzoylthiourea moiety formulated as [Ru(ii)(bpy)
Mona Amiri et al.
Dalton transactions (Cambridge, England : 2003), 49(29), 10173-10184 (2020-07-16)
1,10-Phenanthroline (phen) was grafted to either indium tin oxide (ITO), fluorine-doped tin oxide (FTO), or titanium dioxide (TiO2) semiconductors (SC's) by electrochemical reduction of 5-diazo-phen. The phen ligand is bonded to the semiconductor at C5, and it can be handled
"Phenanthroline diimide as an organic electron-injecting material for organic light-emitting devices"
Lee H, et al.
Royal Society of Chemistry Advances, 2(23), 8762- 8767 (2012)
Kollur Shiva Prasad et al.
Molecules (Basel, Switzerland), 25(12) (2020-06-26)
Herein we report the synthesis and structural elucidation of two novel imine-based ligands, 2-(1,10-phenanthrolin-5-yl)imino)methyl)-5-bromophenol (PIB) and N-(1,10-phenanthrolin-5-yl)-1-(thiophen-3-yl)methanimine (PTM) ligands. An in vitro cytotoxicity assay of the synthesized molecules was carried out against breast, cervical, colorectal, and prostate cancer cell lines
Barbara Feist et al.
Mikrochimica acta, 186(2), 91-91 (2019-01-12)
Graphene oxide (GO) was chemically functionalized with 5-amino-1,10-phenanthroline. The resulting conjugate (phen-GO) was characterized by scanning electron microscopy and X-ray photoelectron spectroscopy. The experiments show that phen-GO has a high affinity for extraction of Pb(II) ions. Isotherms and kinetics fit

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