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661384

Sigma-Aldrich

2-Iodoxybenzoic acid

contains stabilizer, 45 wt. % (IBX)

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Synonym(s):
SIBX, Stabilized IBX
Empirical Formula (Hill Notation):
C7H5IO4
CAS Number:
Molecular Weight:
280.02
MDL number:
PubChem Substance ID:
NACRES:
NA.22

form

solid

Quality Level

contains

stabilizer

reaction suitability

reagent type: oxidant

concentration

45 wt. % (IBX)

SMILES string

OI1(=O)OC(=O)c2ccccc12

InChI

1S/C7H5IO4/c9-7-5-3-1-2-4-6(5)8(10,11)12-7/h1-4H,(H,10,11)

InChI key

CQMJEZQEVXQEJB-UHFFFAOYSA-N

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1 of 4

This Item
I8000I141P26600
2-Iodoxybenzoic acid contains stabilizer, 45 wt. % (IBX)

661384

2-Iodoxybenzoic acid

2-Iodosobenzoic acid

I8000

2-Iodosobenzoic acid

Intralipid 20%, emulsion

I141

Intralipid

2-Phenylindole technical grade, 95%

P26600

2-Phenylindole

reaction suitability

reagent type: oxidant

reaction suitability

-

reaction suitability

-

reaction suitability

-

form

solid

form

powder

form

emulsion

form

powder

contains

stabilizer

contains

-

contains

-

contains

-

concentration

45 wt. % (IBX)

concentration

-

concentration

20%

concentration

-

Application

A stabilized formulation of IBX (SIBX) that displays none of the explosive properties of IBX, while maintaining excellent reactivity and selectivity.
Reagent used to oxidize Fmoc-protected amino alcohols to the corresponding amino aldehydes in the presence of DMSO.

Other Notes

The material is stabilized with benzoic acid and isophthalic acid

signalword

Danger

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1 - STOT RE 1 Inhalation - STOT SE 3

target_organs

Lungs, Respiratory system

supp_hazards

Storage Class

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Aurélie Ozanne et al.
Organic letters, 5(16), 2903-2906 (2003-08-02)
[reaction: see text] SIBX is a nonexplosive formulation of IBX that can be used as a suspension in a variety of standard organic solvents such as refluxing EtOAc and THF to oxidize safely alcohols into aldehydes and ketones. The use
Synthetic Communications, 37, 3493-3493 (2007)
Stefanie Deike et al.
Bioorganic chemistry, 101, 104012-104012 (2020-07-20)
Aggregation of amyloid peptides results in severe neurodegenerative diseases. While the fibril structures of Aβ40 and Aβ42 have been described recently, resolution of the aggregation pathway and evaluation of potent inhibitors still remains elusive, in particular in view of the
Roberta Bernini et al.
Journal of agricultural and food chemistry, 65(31), 6506-6512 (2017-03-14)
A hydroxytyrosol (HTyr)-enriched fraction containing HTyr 6% w/w, derived from Olea europaea L. byproducts and obtained using an environmentally and economically sustainable technology, was lipophilized under green chemistry conditions. The effects of three fractions containing hydroxytyrosyl butanoate, octanoate, and oleate
F Clemente et al.
Bioorganic chemistry, 98, 103740-103740 (2020-03-23)
The enzyme glucocerebrosidase (GCase) has become an important therapeutic target due to its involvement in pathological disorders consequent to enzyme deficiency, such as the lysosomal storage Gaucher disease (GD) and the neurological Parkinson disease (PD). Pharmacological chaperones (PCs) are small

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