687596

(11bR)-(–)-4,4-Dibutyl-4,5-dihydro-2,6-bis(3,4,5-trifluorophenyl)-3H-dinaphth[2,1-c:1′,2′-e]azepinium bromide

Nagase purity

• Empirical Formula (Hill Notation): C₄₂H₃₆BrF₆N
• CAS Number: 887938-70-7
• Molecular Weight: 748.64
• MDL number: MFCD09264271
• UNSPSC Code: 12352005
• PubChem Substance ID: 329761140
• NACRES: NA.22

Properties

• Quality Level: 100
• form: solid
• mp: 223-228 °C
• functional group: fluoro
• SMILES string: CCCC[N+]1(CCCC)Cc2c(cc3ccccc3c2-c4c(C1)c(cc5ccccc45)-c6cc(F)c(F)c(F)c6)-c7cc(F)c(F)c(F)c7
• InChI: 1S/C42H36F6N.BrH/c1-3-5-15-49(16-6-4-2)23-33-31(27-19-35(43)41(47)36(44)20-27)17-25-11-7-9-13-29(25)39(33)40-30-14-10-8-12-26(30)18-32(34(40)24-49)28-21-37(45)42(48)38(46)22-28;/h7-14,17-22H,3-6,15-16,23-24H2,1-2H3;1H/q+1;/p-1
• InChI key: LOMUZNOWQYZTRP-UHFFFAOYSA-M

Description

Application

Potent phase transfer organocatalyst for asymmetric α-alkylation of glycine derivatives at extremely low loadings.

Features and Benefits

Maruoka phase-transfer catalysts are:

• Operationally straightforward
• Environmentally friendly
• Relatively mild reaction conditions
• Reactions conducted in aqueous media
• Low catalyst loading

Legal Information

Product of Nagase & Co. Ltd.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable